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814225 Lithiumdiisopropylamide

(solution about 2 molar in cyclohexane/ethylbenzene/ tetrahydrofuran) for synthesis

Lithiumdiisopropylamide MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents.

Synonyms: Diisopropylaminolithium, LDA

814225
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8142250100
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      		 Glass bottle 100 ml
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      8142259999
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          Description
          Catalogue Number814225
          SynonymsDiisopropylaminolithium, LDA
          References
          Product Information
          HS Code3824 99 92
          Structure formula ImageStructure formula Image
          Quality SegmentMQ200
          Applications
          Biological Information
          Physicochemical Information
          Density0.80 g/cm3 (20 °C)
          Flash point-25 °C
          Dimensions
          Materials Information
          Toxicological Information
          Safety Information according to GHS
          Hazard Pictogram(s) Hazard Pictogram(s)
          Hazard Pictogram(s)
          Hazard Pictogram(s)
          Hazard Pictogram(s)
          Hazard Pictogram(s)
          Hazard Statement(s)H225: Highly flammable liquid and vapour.
          H304: May be fatal if swallowed and enters airways.
          H314: Causes severe skin burns and eye damage.
          H335: May cause respiratory irritation.
          H336: May cause drowsiness or dizziness.
          H351: Suspected of causing cancer.
          H373: May cause damage to organs through prolonged or repeated exposure.
          H410: Very toxic to aquatic life with long lasting effects.
          EUH014: Reacts violently with water.
          EUH019: May form explosive peroxides.
          Precautionary Statement(s)P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
          P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
          P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
          P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
          P304 + P340 + P310: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
          P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
          P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
          Signal WordDanger
          Storage class3 Flammable liquids
          WGKWGK 3 highly hazardous to water
          Disposal26
          Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) dropwise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water dropwise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) dropwise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add dropwise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A.
          Safety Information
          Categories of dangerhighly flammable, corrosive, carcinogenic, dangerous for the environment
          Product Usage Statements
          Storage and Shipping Information
          StorageStore at +2°C to +8°C.
          Packaging Information
          Transport Information
          Declaration (railroad and road) ADR, RIDUN 2924 , 3 (8), II
          Declaration (transport by air) IATA-DGRUN 2924 , 3 (8), II
          Declaration (transport by sea) IMDG-CodeUN 2924 , 3 (8), II, Segregation Group: 18 (Alkalis)
          Supplemental Information
          Specifications
          Assay (acidimetric)26.0 - 34.0 %
          Global Trade ITEM Number
          Catalogue Number GTIN
          8142250100 04022536409825
          8142259999 04022536409832

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          Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Organoelement Compounds > Organometal Compounds
          Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Organoelement Compounds > Hydrides and Amides
          Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Reagents for Organometallic Synthesis
          Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Organoelement Compounds > Hydrides and Amides
          Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Products for Pharma > Organic Synthesis Building Blocks and Reagents for Pharma > Organoelement Compounds > Organometal Compounds