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814225 Lithiumdiisopropylamide

(solution about 2 molar in cyclohexane/ethylbenzene/ tetrahydrofuran) for synthesis

Lithiumdiisopropylamide MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents.

Synonyms: Diisopropylaminolithium, LDA

814225
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      		 Glass bottle 100 ml
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      Description
      Catalogue Number814225
      SynonymsDiisopropylaminolithium, LDA
      References
      Product Information
      HS Code3824 99 92
      Structure formula ImageStructure formula Image
      Quality SegmentMQ200
      Applications
      Biological Information
      Physicochemical Information
      Density0.80 g/cm3 (20 °C)
      Flash point-25 °C
      Dimensions
      Materials Information
      Toxicological Information
      Safety Information according to GHS
      Hazard Pictogram(s) Hazard Pictogram(s)
      Hazard Pictogram(s)
      Hazard Pictogram(s)
      Hazard Pictogram(s)
      Hazard Pictogram(s)
      Hazard Statement(s)H225: Highly flammable liquid and vapour.
      H304: May be fatal if swallowed and enters airways.
      H314: Causes severe skin burns and eye damage.
      H335: May cause respiratory irritation.
      H336: May cause drowsiness or dizziness.
      H351: Suspected of causing cancer.
      H373: May cause damage to organs through prolonged or repeated exposure.
      H410: Very toxic to aquatic life with long lasting effects.
      EUH014: Reacts violently with water.
      EUH019: May form explosive peroxides.
      Precautionary Statement(s)P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
      P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
      P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
      P303 + P361 + P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
      P304 + P340 + P310: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
      P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
      P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
      Signal WordDanger
      Storage class3 Flammable liquids
      WGKWGK 3 highly hazardous to water
      Disposal26
      Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) dropwise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water dropwise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) dropwise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add dropwise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A.
      Safety Information
      Categories of dangerhighly flammable, corrosive, carcinogenic, dangerous for the environment
      Product Usage Statements
      Storage and Shipping Information
      StorageStore at +2°C to +8°C.
      Packaging Information
      Transport Information
      Declaration (railroad and road) ADR, RIDUN 2924 , 3 (8), II
      Declaration (transport by air) IATA-DGRUN 2924 , 3 (8), II
      Declaration (transport by sea) IMDG-CodeUN 2924 , 3 (8), II, Segregation Group: 18 (Alkalis)
      Supplemental Information
      Specifications
      Assay (acidimetric)26.0 - 34.0 %
      Global Trade ITEM Number
      Catalogue Number GTIN
      8142250100 04022536409825

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