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Merck

1.06054

Dichloromethane

for gas chromatography ECD and FID SupraSolv®

Synonym(s):

DCM, Methylene chloride, Methylene dichloride, Methylene chloride

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About This Item

Linear Formula:
CH2Cl2
CAS Number:
Molecular Weight:
84.93
UNSPSC Code:
12191502
NACRES:
NA.03
EC Index Number:
200-838-9
MDL number:
Beilstein/REAXYS Number:
1730800
Assay:
≥99.8% (GC)
Technique(s):
gas chromatography (GC): suitable
Bp:
39.8-40 °C (lit.)
Vapor pressure:
24.45 psi ( 55 °C), 6.83 psi ( 20 °C)
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Quality Segment

vapor density

2.9 (vs air)

vapor pressure

24.45 psi ( 55 °C), 6.83 psi ( 20 °C)

product line

SupraSolv®

assay

≥99.8% (GC)

form

liquid

autoignition temp.

1223 °F, 605 °C (DIN 51794)

potency

1600 mg/kg LD50, oral (Rat), >2000 mg/kg LD50, skin (Rat)

contains

2-Methyl-2-butene as stabilizer

expl. lim.

22 %

technique(s)

gas chromatography (GC): suitable

refractive index

n20/D 1.424 (lit.)

pH

7 (20 °C)

bp

39.8-40 °C (lit.)

mp

-95 °C, −95 °C (lit.)

solubility

20 g/L

density

1.325 g/mL at 25 °C (lit.)

storage temp.

2-30°C

SMILES string

ClCCl

InChI

1S/CH2Cl2/c2-1-3/h1H2

InChI key

YMWUJEATGCHHMB-UHFFFAOYSA-N

General description

SupraSolv® ECD and FID is a high-purity solvent grade specifically formulated for sample preparation in gas chromatography with electron capture (ECD) and flame ionization (FID) detection.ECD and FID impose distinct and stringent solvent purity requirements. The electron capture detector is exquisitely sensitive to electronegative species — particularly halogenated compounds — at sub-nanogram concentrations, while the flame ionization detector responds to any carbon-containing organic impurity undergoing combustion. SupraSolv® ECD and FID solvents are therefore subjected to rigorous purification and detector-specific testing protocols to ensure that intrinsic solvent impurities remain below the respective detection thresholds of both detector types simultaneously.

Application

These solvents are routinely employed in PCB and organochlorine determination in water and soil, pesticide residue analysis in food and environmental matrices, dioxin screening, and hydrocarbon index measurements — applications where detector sensitivity demands the highest attainable solvent purity to ensure method selectivity and regulatory compliance.

Analysis Note

SupraSolv® ECD and FID solvents are tested and certified against stringent detector-specific purity thresholds across defined chromatographic retention time windows, including:• GC-ECD (early retention window): ≤ 1 ng/mL relative to tetrachloromethane• GC-ECD (late retention window): ≤ 2 pg/mL relative to lindane• GC-FID: ≤ 2 ng/mL relative to n-tetradecane

Other Notes

Explore various lab safety accessories and equipment for safe handling of solvents to increase your safety level from the first usage.

Legal Information

SUPRASOLV is a registered trademark of Merck KGaA, Darmstadt, Germany


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pictograms

Health hazardExclamation mark

signalword

Warning

Hazard Classifications

Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Central nervous system

Storage Class

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk

WGK 2



Certificates of Analysis (COA)

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