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Merck

294837

Hydrogen chloride solution

1.0 M in diethyl ether

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About This Item

Empirical Formula (Hill Notation):
HCl
CAS Number:
Molecular Weight:
36.46
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352301
MDL number:
Concentration:
0.95-1.10 M (with NaOH, titration), 1.0 M in diethyl ether
Form:
liquid
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form

liquid

Quality Level

concentration

0.95-1.10 M (with NaOH, titration), 1.0 M in diethyl ether

density

0.731 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

Cl

InChI

1S/ClH/h1H

InChI key

VEXZGXHMUGYJMC-UHFFFAOYSA-N

General description

Hydrogen chloride solution (1.0 M in diethyl ether) is generally prepared by passing HCl gas through diethyl ether solvent. It is suitable for air/moisture-sensitive reactions.

Application

Hydrogen chloride solution (1.0 M in diethyl ether) can be used in the synthesis of molybdenum adamantylimido and t-butylimido alkylidene chloride complexes in the presence of PPh2Me. It is also used in some cyclization reactions, for example, in the cyclization of oxadiazole derivatives from corresponding thiosemicarbazides.


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Danger

Hazard Classifications

Acute Tox. 4 Oral - Flam. Liq. 2 - Met. Corr. 1 - STOT SE 3

target_organs

Central nervous system

supp_hazards

Storage Class

3 - Flammable liquids

wgk

WGK 1

flash_point_f

-40.0 °F - closed cup

flash_point_c

-40 °C - closed cup



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Xuan Zhang et al.
Nanomedicine : nanotechnology, biology, and medicine, 11(6), 1365-1375 (2015-04-19)
Intratumoral injection of ultra-small gold nanoparticles (AuNPs) conjugated to doxorubicin (Au-Dox) is effective against both murine B16 and human SK-MEL-28 tumors in mice. Au-Dox suppresses growth of B16 tumors in immunocompetent mice by >70% for at least 19 days. In
Thomas Krohn et al.
European journal of nuclear medicine and molecular imaging, 42(2), 210-214 (2014-09-25)
To determine the frequency of seemingly pathological retroperitoneal uptake in the location of the coeliac ganglia in patients undergoing [(68)Ga]PSMA-HBED PET/CT. The study included 85 men with prostate cancer referred for [(68)Ga]PSMA-HBED PET/CT. The PET/CT scans were evaluated for the
Jay G Hosking et al.
Neuropsychopharmacology : official publication of the American College of Neuropsychopharmacology, 40(4), 1005-1015 (2014-10-21)
Successful decision making often requires weighing a given option's costs against its associated benefits, an ability that appears perturbed in virtually every severe mental illness. Animal models of such cost/benefit decision making overwhelmingly implicate mesolimbic dopamine in our willingness to