Millipore Sigma Vibrant Logo

807246 1,4-Phenylenediamine

1,4-Phenylenediamine for synthesis. CAS 106-50-3, pH 9 (50 g/l, H₂O, 20 °C).

1,4-Phenylenediamine MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents.
CAS #: 106-50-3 EC Number: 203-404-7 Molar Mass: 108.14 g/mol Hill Formula: C₆H₈N₂
View Products on Sigmaaldrich.com
807246
View Pricing & Availability

Overview

Replacement Information

Key Spec Table

CAS #EC NumberHill FormulaMolar Mass
106-50-3203-404-7C₆H₈N₂108.14 g/mol

Pricing & Availability

Catalogue Number AvailabilityPackaging Qty/Pack Price Quantity
8072460005
Retrieving availability...
—
Limited Availability Limited Availability
In Stock 
Discontinued
Limited Quantities Available
Availability to be confirmed
    Remaining : Will advise
      Remaining : Will advise
      Will advise
      Contact Customer Service
      Contact Customer Service

      		 Glass bottle 5 g
      Retrieving price...
      Price could not be retrieved
      Minimum Quantity is a multiple of
      Maximum Quantity is
      Upon Order Completion More Information
      You Saved ()
       
      —
      Request Pricing
      		 —
      8072460250
      Retrieving availability...
      —
      Limited Availability Limited Availability
      In Stock 
      Discontinued
      Limited Quantities Available
      Availability to be confirmed
        Remaining : Will advise
          Remaining : Will advise
          Will advise
          Contact Customer Service
          Contact Customer Service

          		 Glass bottle 250 g
          Retrieving price...
          Price could not be retrieved
          Minimum Quantity is a multiple of
          Maximum Quantity is
          Upon Order Completion More Information
          You Saved ()
           
          —
          Request Pricing
          		 —
          8072461000
          Retrieving availability...
          —
          Limited Availability Limited Availability
          In Stock 
          Discontinued
          Limited Quantities Available
          Availability to be confirmed
            Remaining : Will advise
              Remaining : Will advise
              Will advise
              Contact Customer Service
              Contact Customer Service

              		 Glass bottle 1 kg
              Retrieving price...
              Price could not be retrieved
              Minimum Quantity is a multiple of
              Maximum Quantity is
              Upon Order Completion More Information
              You Saved ()
               
              —
              Request Pricing
              		 —
              8072469025
              Retrieving availability...
              —
              Limited Availability Limited Availability
              In Stock 
              Discontinued
              Limited Quantities Available
              Availability to be confirmed
                Remaining : Will advise
                  Remaining : Will advise
                  Will advise
                  Contact Customer Service
                  Contact Customer Service

                  		 Plastic drum 25 kg
                  Retrieving price...
                  Price could not be retrieved
                  Minimum Quantity is a multiple of
                  Maximum Quantity is
                  Upon Order Completion More Information
                  You Saved ()
                   
                  —
                  Request Pricing
                  		 —
                  Description
                  Catalogue Number807246
                  References
                  Product Information
                  CAS number106-50-3
                  EC index number612-028-00-6
                  EC number203-404-7
                  Hill FormulaC₆H₈N₂
                  Molar Mass108.14 g/mol
                  HS Code2921 51 19
                  Structure formula ImageStructure formula Image
                  Quality SegmentMQ200
                  Applications
                  Application1,4-Phenylenediamine for synthesis. CAS 106-50-3, pH 9 (50 g/l, H₂O, 20 °C).
                  Biological Information
                  Physicochemical Information
                  Boiling point267 °C (1013 hPa)
                  Density0.726 g/cm3 (22 °C)
                  Flash point110 °C
                  Ignition temperature567 °C
                  Melting Point139 - 141 °C
                  pH value9 (50 g/l, H₂O, 20 °C)
                  Vapor pressure1.44 hPa (100 °C)
                  Bulk density600 kg/m3
                  Solubility47 g/l
                  Dimensions
                  Materials Information
                  Toxicological Information
                  LD 50 oralLD50 Rat 80 mg/kg
                  LD 50 dermalLD50 Rabbit > 7940 mg/kg
                  Safety Information according to GHS
                  Hazard Pictogram(s) Hazard Pictogram(s)
                  Hazard Pictogram(s)
                  Hazard Pictogram(s)
                  Hazard Statement(s)H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled.
                  H317: May cause an allergic skin reaction.
                  H319: Causes serious eye irritation.
                  H370: Causes damage to organs if swallowed.
                  H410: Very toxic to aquatic life with long lasting effects.
                  Precautionary Statement(s)P273: Avoid release to the environment.
                  P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.
                  P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor.
                  P302 + P352 + P312: IF ON SKIN: Wash with plenty of water. Call a POISON CENTER/doctor if you feel unwell.
                  P304 + P340 + P311: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor.
                  P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
                  Signal WordDanger
                  RTECSSS8050000
                  Storage class6.1D Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
                  WGKWGK 3 highly hazardous to water
                  Safety Information
                  Categories of dangertoxic, irritant, sensitizing, dangerous for the environment
                  Product Usage Statements
                  Storage and Shipping Information
                  StorageStore below +30°C.
                  Packaging Information
                  Transport Information
                  Declaration (railroad and road) ADR, RIDUN 1673 , 6.1, III
                  Declaration (transport by air) IATA-DGRUN 1673 , 6.1, III
                  Declaration (transport by sea) IMDG-CodeUN 1673 , 6.1, III
                  Supplemental Information
                  Specifications
                  Assay (GC, area%)≥ 98.0 % (a/a)
                  Identity (IR)passes test
                  Global Trade ITEM Number
                  Catalogue Number GTIN
                  8072460005 04022536394381
                  8072460250 04022536394398
                  8072461000 04022536394404
                  8072469025 04022536394411

                  Documentation

                  1,4-Phenylenediamine SDS

                  Title

                  Safety Data Sheet (SDS) 

                  1,4-Phenylenediamine Certificates of Analysis

                  Product Number PackagingLot Number
                  8072460005 Glass bottle
                  8072460250 Glass bottle
                  8072461000 Glass bottle
                  8072469025 Plastic drum

                  Related Products & Applications

                  Categories

                  Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Products for Other Technical Applications
                  Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Polyaddition Reagents
                  Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Polycondensation Reagents
                  Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Product Groups > Amines and Ammonium Compounds > Aromatic and Heteroaromatic Amines > Primary Aromatic Amines (Anilines)
                  Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Amines and Ammonium Compounds > Aromatic and Heteroaromatic Amines > Primary Aromatic Amines (Anilines)
                  Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Polyaddition Reagents
                  Reagents, Chemicals and Labware > Organic Synthesis > Organic Synthesis Products for Pharma > Organic Synthesis Building Blocks and Reagents for Pharma > Amines and Ammonium Compounds > Aromatic and Heteroaromatic Amines > Primary Aromatic Amines (Anilines)
                  Reagents, Chemicals and Labware > Organic Synthesis > Product Line for synthesis > Polycondensation Reagents