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Merck

207942

Hydrazine monohydrate

N2H4 64-65 %, reagent grade, ≥97%

Synonym(s):

Hydrazinium hydroxide

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About This Item

Linear Formula:
NH2NH2 · H2O
CAS Number:
7803-57-8
Molecular Weight:
50.06
UNSPSC Code:
12352300
NACRES:
NA.21
PubChem Substance ID:
24852482
EC Number:
206-114-9
Beilstein/REAXYS Number:
878137
MDL number:
MFCD00149931
Assay:
≥97%
Grade:
reagent grade
Form:
liquid

Key Documents

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InChI key

IKDUDTNKRLTJSI-UHFFFAOYSA-N

InChI

1S/H4N2.H2O/c1-2;/h1-2H2;1H2

SMILES string

O.NN

grade

reagent grade

vapor density

>1 (vs air)

vapor pressure

5 mmHg ( 25 °C)

assay

≥97%

form

liquid

composition

N2H4, 64-65%

expl. lim.

99.99 %

refractive index

n20/D 1.428 (lit.)

pH

10.6-10.7 (10 g/L)

bp

120.1 °C (lit.)

mp

−51.7 °C (lit.)

density

1.032 g/mL at 25 °C (lit.)

Quality Level

100

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General description

Crystals of hydrazine monohydrate exhibit triclinic crystal system and space group P3121.

Application

Hydrazine monohydrate has been used to synthesize 2-(6-ethylamino-3-ethylimino-2,7-dimethyl-3H-xanthen-9-yl)benzoic acid hydrazide and vinyl-benzylamine hydrochloride. It may also be used as a source of hydrogen via decomposition in the presence of supported bimetallic catalyst composed of Ni-Pt alloy nanoparticles and mesoporous CeO2 support.
Hydrazine monohydrate may be used as a reducing agent for the reduction of:
  • Nitroarenes in the presence of hydrogen peroxide functionalized carbon nanotubes.
  • 4-Iodo-3-nitroanisole to form 2-iodo-5-methoxyaniline.
  • Graphene oxide (GO) to form graphene.

signalword

Danger

Storage Class

3 - Flammable liquids

flash_point_f

100.4 °F - closed cup - (anhydrous substance)

flash_point_c

38 °C - closed cup - (anhydrous substance)

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - Skin Sens. 1

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Deleterious substance

pdsc

Class I Designated Chemical Substances

prtr

Group 4: Flammable liquids + Type 3 petroleums + Hazardous rank III + Water insoluble liquid

fsl

Substances Subject to be Indicated Names

ishl_indicated

Substances Subject to be Notified Names

ishl_notified

207942-500G:4548173114972 + 207942-2.5L: + 207942-BULK: + 207942-100G:4548173114958 + 207942-5G:4548173114989 + 207942-4X100G: + 207942-3ML-LBL: + 207942-3ML-KC: + 207942-5ML: + 207942-VAR: + 207942-2KG:4548173952963 + 207942-1L: + 207942-500ML: + 207942-100ML: + 207942-2.5KG:4548173114965

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Certificates of Analysis (COA)

Lot/Batch Number
MKCQ9601
BCCG8298
MKCQ1938
BCCG3447
MKCN8255

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Convergent synthesis of the quinolone substructure of BILN 2061 via carbonylative Sonogashira coupling/cyclization.
Haddad N, et al.
The Journal of Organic Chemistry, 71(13), 5031-5034 (2006)
Carbon nanotubes oxidized by a green method as efficient metal-free catalysts for nitroarene reduction.
Wu S, et al.
Physical Chemistry Chemical Physics, 17(3), 1567-1571 (2015)
High performance supercapacitor for efficient energy storage under extreme environmental temperatures.
Vellacheri R, et al.
Nano Energy, 8, 231-237 (2014)
Yuan-Yuan Jiang et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(43), 15439-15445 (2015-10-17)
The development of active, selective, and robust catalysts is a key issue in promoting the practical application of hydrazine monohydrate (N2 H4 ⋅H2 O) as a viable hydrogen carrier. Herein, the synthesis of a supported Ni-Pt bimetallic nanocatalyst on mesoporous
Young-Keun Yang et al.
Nature protocols, 2(7), 1740-1745 (2007-07-21)
This protocol describes detailed procedures for the preparation of a rhodamine-based mercury probe and for its applications to the detection of mercury in cells and vertebrate organisms. The mercury probe 1, which is prepared in two steps from rhodamine 6G
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