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Merck

402974

Lithium hydroxide monohydrate

greener alternative

ACS reagent, ≥98.0%

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About This Item

Linear Formula:
LiOH · H2O
CAS Number:
Molecular Weight:
41.96
NACRES:
NB.24
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
215-183-4
MDL number:
Assay:
≥98.0%
Grade:
ACS reagent
Form:
powder, crystals or granules
Solubility:
water: soluble 216 g/L at 20 °C
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grade

ACS reagent

Quality Level

assay

≥98.0%

form

powder, crystals or granules

greener alternative product characteristics

Design for Energy Efficiency
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sustainability

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impurities

≤0.01% insolubles, ≤2.0% Li2CO3

pH

12 (0.4 g/L)

solubility

water: soluble 216 g/L at 20 °C

anion traces

chloride (Cl-): ≤0.01%, sulfate (SO42-): ≤0.05%

cation traces

Fe: ≤0.002%, heavy metals: ≤20 ppm (by ICP-OES)

greener alternative category

storage temp.

room temp

SMILES string

[Li+].O.[OH-]

InChI

1S/Li.2H2O/h;2*1H2/q+1;;/p-1

InChI key

GLXDVVHUTZTUQK-UHFFFAOYSA-M

General description

We are committed to bringing you Greener Alternative Products, which belong to one of the four categories of greener alternatives. Lithium hydroxide monohydrate supports cleaner technologies as a key precursor for high-performance lithium-ion batteries. Click here for more information.
Lithium hydroxide monohydrate is a lithium salt. Crystal structure study reveals it has monoclinic structure with space group C2/m. Its vibrational spectra has been studied using IR, Raman and inelastic neutron scattering (INS) spectroscopy. It is reported to transform the surface of titania monoliths to form flower like structures.

Application

Lithium hydroxide monohydrate may be used to produce naphtoxy ion during the synthesis of allyl 1-naphthyl ethers.
It may be used in the synthesis of the following:
  • Lithium titanate (Li4Ti5O12) heterogeneous nanostructures.
  • Tin oxide-carbon (SnO2/C) nanocomposites.
  • Zinc oxide (ZnO) nanowire arrays.
  • Lithium diborate gel films.
  • Porous layered lithium cobalt oxide (LiCoO2) films.


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pictograms

CorrosionExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Deleterious substance

pdsc

Substances Subject to be Notified Names

ishl_notified

402974-2KG:4.548173940168E12 + 402974-25G:4.548173940151E12 + 402974-500G:4.548173940175E12

jan



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Articles

エネルギー貯蔵システムにおけるニッケルリッチ層状酸化物正極材料の課題と製造プロセスについて説明しています。

Experts discuss challenges and production processes of nickel-rich layered oxide cathode materials in energy storage systems.


Synthesis of heterogeneous Li4Ti5O12 nanostructured anodes with long-term cycle stability.
Lee DK, et al.
Nanoscale Research Letters, 5(10), 1585-1589 (2010)
Flower-like surface modification of titania materials by lithium hydroxide solution.
Hasegawa G, et al.
Journal of Colloid and Interface Science, 374(1), 291-296 (2012)
Optimization of the ultrasound-assisted synthesis of allyl 1-naphthyl ether using response surface methodology.
dos Santos Fernandes JP, et al.
Ultrasonics Sonochemistry, 18(2), 489-493 (2011)