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72017

Sodium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

Selectophore™

Synonym(s):

NaBARF, Tetrakis[3,5-bis(trifluoromethyl)phenyl]boron sodium

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About This Item

Empirical Formula (Hill Notation):
C32H12BF24Na
CAS Number:
79060-88-1
Molecular Weight:
886.20
UNSPSC Code:
26111700
NACRES:
NB.61
PubChem Substance ID:
329763706
MDL number:
MFCD00043323
Beilstein/REAXYS Number:
5474788
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Quality Level

200

description

for ion-selective electrodes

product line

Selectophore™

assay

≥95.0% (based on Na and calc. on dry substance, AAS)

form

powder

SMILES string

[Na+].FC(F)(F)c1cc(cc(c1)C(F)(F)F)[B-](c2cc(cc(c2)C(F)(F)F)C(F)(F)F)(c3cc(cc(c3)C(F)(F)F)C(F)(F)F)c4cc(cc(c4)C(F)(F)F)C(F)(F)F

InChI

1S/C32H12BF24.Na/c34-25(35,36)13-1-14(26(37,38)39)6-21(5-13)33(22-7-15(27(40,41)42)2-16(8-22)28(43,44)45,23-9-17(29(46,47)48)3-18(10-23)30(49,50)51)24-11-19(31(52,53)54)4-20(12-24)32(55,56)57;/h1-12H;/q-1;+1

InChI key

LTGMONZOZHXAHO-UHFFFAOYSA-N

General description

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Sodium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate is a lipophilic ion which is insoluble in water. It is also strong against acids and oxidants. It can be prepared using boron trifluoride and 3,5-bis(trifluoromethyl)phenylmagnesium iodide as major components.

Application

Sodium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate was used in the preparation of poly(n-butyl acrylate)- based ion-selective membranes.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Analysis Note

can contain 1-5% water

Other Notes

Lipophilic additive for solvent polymeric membrane electrodes and optodes; Highly lipophilic analogue of tetraphenylborate used for solvent extraction of cations; Anionic phase-transfer catalyst

Legal Information

Selectophore is a trademark of Merck KGaA, Darmstadt, Germany

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Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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W.E. Morf
Analytical Chemistry, 62, 738-738 (1990)
H. Nishada et al.
Bulletin of the Chemical Society of Japan, 57, 2600-2600 (1984)
Y. Shiraki et al.
Bulletin of the Chemical Society of Japan, 58, 3041-3041 (1985)
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