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Merck

8.14283

Bis(trichloromethyl) carbonate

for synthesis

Synonym(s):

Bis(trichloromethyl) carbonate, Triphosgene, Carbonic acid bistrichlor methyl ester

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About This Item

Linear Formula:
(Cl3CO)2CO
CAS Number:
Molecular Weight:
296.75
UNSPSC Code:
12352108
EC Index Number:
250-986-3
NACRES:
NA.22
MDL number:
Form:
crystals
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vapor pressure

16 hPa ( 90 °C)

Quality Segment

form

crystals

bp

203-206 °C/1013 mbar

mp

77-81 °C

density

1.6 g/cm3 at 20 °C

storage temp.

2-30°C

SMILES string

ClC(Cl)(Cl)OC(=O)OC(Cl)(Cl)Cl

InChI

1S/C3Cl6O3/c4-2(5,6)11-1(10)12-3(7,8)9

InChI key

UCPYLLCMEDAXFR-UHFFFAOYSA-N

Application


  • Triphosgene in Organic Synthesis: Triphosgene is highlighted for its efficacy in organic reactions over the last decade, offering a safer and more convenient alternative to phosgene due to its solid state and lower volatility. so it can be used in various synthetic applications, enhancing reaction conditions and safety in laboratories(Ganiu et al., 2020).

  • Biodegradable Hydrogel Synthesis: Bis(trichloromethyl) carbonate was utilized in the one-step synthesis of biodegradable curcumin-derived hydrogels aimed at soft tissue filler applications post-breast cancer surgery. This represents a significant advancement in biomaterials, focusing on improving post-surgical recovery and compatibility (Shpaisman et al., 2012).

Analysis Note

Assay (ex Cl): ≥ 96.0 %
Melting range (lower value): ≥ 76 °C
Melting range (upper value): ≤ 81 °C
Identity (IR): passes test


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pictograms

CorrosionSkull and crossbones

signalword

Danger

Hazard Classifications

Acute Tox. 1 Inhalation - Skin Corr. 1B

Storage Class

6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable



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