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Merck

308315

Lithium hexafluoroarsenate(V)

greener alternative

98%

Synonym(s):

Hexafluoroarsenate(V) lithium

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About This Item

Linear Formula:
LiAsF6
CAS Number:
29935-35-1
Molecular Weight:
195.85
NACRES:
NA.23
PubChem Substance ID:
24858666
UNSPSC Code:
12352302
EC Number:
249-963-0
MDL number:
MFCD00011076
Assay:
98%
Form:
powder

Key Documents

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form

powder

assay

98%

InChI key

GTZQZEYBOGZTEO-UHFFFAOYSA-N

InChI

1S/AsF6.Li/c2-1(3,4,5,6)7;/q-1;+1

SMILES string

[Li+].F[As-](F)(F)(F)(F)F

reaction suitability

core: lithium, reagent type: catalyst

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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application(s)

battery precursors
catalysts
material synthesis precursor

greener alternative category

Enabling,

Quality Level

100

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General description

Lithium hexafluoroarsenate(V) is a class of electrolytic materials that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

The surface chemistry of Li electrodes in ethereal LiAsF6 was tested with new salts for potential battery systems.

pictograms

Skull and crossbonesEnvironment
GHS06,GHS09

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
MKCQ6116
MKCN0727
MKCL7755
MKCF1718
MKCG1095

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Ling-Yun Yang et al.
Angewandte Chemie (International ed. in English), 53(14), 3631-3635 (2014-03-07)
A new category of crystalline polymer electrolyte prepared by the supramolecular self-assembly of polyethylene oxide (PEO), α-cyclodextrin (α-CD), and LiAsF6 is reported. The polymer electrolyte consists of the nanochannels formed by α-CDs in which the PEO/Li(+) complexes are confined. The
The Li-ion rechargeable battery: a perspective
Goodenough JB and Park K
Journal of the American Chemical Society, 135(4), 1167-1176 (2013)
Electrodes with high power and high capacity for rechargeable lithium batteries
Kang K, et al.
Science, 311(5763), 977-980 (2006)
Challenges for rechargeable Li batteries
Goodenough JB and Kim Y
Chemistry of Materials, 22(3), 587-603 (2009)
Towards greener and more sustainable batteries for electrical energy storage
Larcher D and Tarascon J
Nature Chemistry, 7(1), 19-19 (2015)

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