L511692
2:1 2,2′-Bipyridine:Cyclopentadienyl(n6-naphthalene)ruthenium(II) hexafluorophosphate
AldrichCPR
Synonym(s):
Herzon Hydration Catalyst
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About This Item
Empirical Formula (Hill Notation):
C25H21N2Ru · PF6
Molecular Weight:
595.48
PubChem Substance ID:
UNSPSC Code:
12352200
NACRES:
NA.21
Quality Segment
SMILES string
F[P-](F)(F)(F)(F)F.C1(C2=NC=CC=C2)=CC=CC=N1.C3(C4=NC=CC=C4)=CC=CC=N3.[C]56[C][C][C][C][C]5C=CC=C6.[Ru+].[C]7[C][C][C][C]7
InChI
1S/2C10H8N2.C10H8.C5H5.F6P.Ru/c2*1-3-7-11-9(5-1)10-6-2-4-8-12-10;1-2-6-10-8-4-3-7-9(10)5-1;1-2-4-5-3-1;1-7(2,3,4,5)6;/h2*1-8H;1-8H;1-5H;;/q;;;;-1;+1
InChI key
YFGQTOCRCOVSBH-UHFFFAOYSA-N
Application
Ready mixed, single catalyst system developed by the Herzon Group for terminal alkyne functionalization. Used recently by that group to affect the anti-Markovnikov reductive hydration alkynes.
Temporal separation of catalytic activities allows anti-Markovnikov reductive functionalization of terminal alkynes
Temporal separation of catalytic activities allows anti-Markovnikov reductive functionalization of terminal alkynes
Other Notes
Please note that Sigma-Aldrich provides this product to early discovery researchers as part of a collection of unique chemicals. Sigma-Aldrich does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final.
NOTWITHSTANDING ANY CONTRARY PROVISION CONTAINED IN SIGMA-ALDRICH′S STANDARD TERMS AND CONDITIONS OF SALE OR AN AGREEMENT BETWEEN SIGMA-ALDRICH AND BUYER, SIGMA-ALDRICH SELLS THIS PRODUCT "AS-IS" AND MAKES NO REPRESENTATION OR WARRANTY WHATSOEVER WITH RESPECT TO THIS PRODUCT, INCLUDING ANY (A) WARRANTY OF MERCHANTABILITY; (B) WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE; OR (C) WARRANTY AGAINST INFRINGEMENT OF INTELLECTUAL PROPERTY RIGHTS OF A THIRD PARTY; WHETHER ARISING BY LAW, COURSE OF DEALING, COURSE OF PERFORMANCE, USAGE OF TRADE OR OTHERWISE.
NOTWITHSTANDING ANY CONTRARY PROVISION CONTAINED IN SIGMA-ALDRICH′S STANDARD TERMS AND CONDITIONS OF SALE OR AN AGREEMENT BETWEEN SIGMA-ALDRICH AND BUYER, SIGMA-ALDRICH SELLS THIS PRODUCT "AS-IS" AND MAKES NO REPRESENTATION OR WARRANTY WHATSOEVER WITH RESPECT TO THIS PRODUCT, INCLUDING ANY (A) WARRANTY OF MERCHANTABILITY; (B) WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE; OR (C) WARRANTY AGAINST INFRINGEMENT OF INTELLECTUAL PROPERTY RIGHTS OF A THIRD PARTY; WHETHER ARISING BY LAW, COURSE OF DEALING, COURSE OF PERFORMANCE, USAGE OF TRADE OR OTHERWISE.
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Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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