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Merck

1.03792

Ammonium iron(II) sulfate hexahydrate

for analysis EMSURE® ISO

Synonym(s):

Ammonium iron(II) sulfate hexahydrate

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About This Item

Empirical Formula (Hill Notation):
H8FeN2O8S2 · 6H2O
CAS Number:
Molecular Weight:
392.14
UNSPSC Code:
12352302
EC Index Number:
233-151-8
NACRES:
NA.21
MDL number:
Assay:
99.0-101.5% (manganometric)
Form:
solid
Solubility:
269 g/L
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agency

reag. ISO

Quality Segment

product line

EMSURE®

assay

99.0-101.5% (manganometric)

form

solid

potency

3250 mg/kg LD50, oral (Rat)

pH

3.0-5.0 (25 °C, 5% in water)

mp

39-41 °C (decomposition)

solubility

269 g/L

density

1.86 g/cm3 at 20 °C

bulk density

900 kg/m3

anion traces

chloride (Cl-): ≤0.001%, phosphate (PO43-): ≤0.002%

cation traces

Ca: ≤0.002%, Cu: ≤0.002%, Fe3+: ≤0.02%, K: ≤0.01%, Mg: ≤0.01%, Mn: ≤0.05%, Na: ≤0.01%, Pb: ≤0.001%, Zn: ≤0.003%

storage temp.

15-25°C

SMILES string

[Fe+3].[S](=O)(=O)([O-])[O-].[S](=O)(=O)([O-])[O-].[N+H4].[N+H4].O.O.O.O.O.O

InChI

1S/Fe.2H3N.2H2O4S.6H2O/c;;;2*1-5(2,3)4;;;;;;/h;2*1H3;2*(H2,1,2,3,4);6*1H2/q+3;;;;;;;;;;/p-2

InChI key

SHHFGSWBFZVUNE-UHFFFAOYSA-L

Application


  • Water-Mediated Green and Efficient Synthesis of Bis(Indolyl)methanes Using Ammonium Iron(II) Sulfate.: This research highlights the use of ammonium iron(II) sulfate hexahydrate in the green synthesis of bis(indolyl)methanes. The study demonstrates the compound′s efficiency and eco-friendliness in catalyzing reactions in water, offering a sustainable alternative in organic synthesis (Letters in Organic Chemistry, 2020).


  • Determination of Ferromanganese and Ferrosilicon by Ammonium Ferrous Sulfate Titration and ICP.: This paper discusses the analytical methods for determining ferromanganese and ferrosilicon using ammonium iron(II) sulfate titration and inductively coupled plasma (ICP). The study underscores the compound′s role in precise quantitative analysis in metallurgical processes (Modern Analytical Chemistry Research, 2020).



Analysis Note

Assay (manganometric): 99.0 - 101.5 %


pH-value (5%; water; 25°C) 3.0 - 5.0


Chloride (Cl): ≤ 0.001 %


Phosphate (PO₄): ≤ 0.002 %


Iron(III)-salts (Fe³⁺): ≤ 0.02 %


Ca (Calcium): ≤ 0.002 %


Cu (Copper): ≤ 0.002 %


K (Potassium): ≤ 0.01 %


Mg (Magnesium): ≤ 0.01 %


Mn (Manganese): ≤ 0.05 %


Na (Sodium): ≤ 0.01 %


Pb (Lead): ≤ 0.001 %


Zn (Zinc): ≤ 0.003 %


Corresponds to ISO

Legal Information

EMSURE is a registered trademark of Merck KGaA, Darmstadt, Germany


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Storage Class

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable



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