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Merck

30417

Ácido fosfórico

greener alternative

puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥85%

Sinónimos:

Ácido ortofosfórico

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Fórmula lineal:
H3PO4
Número CAS:
Peso molecular:
98.00
EC Number:
231-633-2
UNSPSC Code:
12352106
PubChem Substance ID:
Beilstein/REAXYS Number:
1921286
MDL number:
Assay:
≥85%
Form:
liquid
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InChI key

NBIIXXVUZAFLBC-UHFFFAOYSA-N

InChI

1S/H3O4P/c1-5(2,3)4/h(H3,1,2,3,4)

SMILES string

OP(O)(O)=O

grade

ACS reagent, puriss. p.a.

agency

USP/NF, reag. ISO, reag. Ph. Eur.

vapor density

3.4 (vs air)

vapor pressure

2.2 mmHg ( 20 °C), 5 mmHg ( 25 °C)

assay

≥85%

form

liquid

Quality Level

Gene Information

human ... SRC(6714)

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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impurities

reducing impurities, in accordance, residual solvents, in accordance, substances precipitated by ammonia, in accordance, ≤0.001% KMnO4 red. matter (as O), ≤0.001% heavy metals (as Pb), ≤0.001% in water insoluble matters, ≤0.001% volatile acids (as CH3COOH)

bp

158 °C (lit.)

mp

~40 °C (lit.)

density

1.685 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤2 mg/kg, fluoride (F-): ≤1 mg/kg, nitrate (NO3-): ≤3 mg/kg, phosphite, hypophosphite (as H3PO3): ≤20 mg/kg, phosphite, hypophosphite (as H3PO3): in accordance, sulfate (SO42-): ≤30 mg/kg

cation traces

As: ≤0.5 mg/kg, Ca: ≤10 mg/kg, Cd: ≤1 mg/kg, Co: ≤1 mg/kg, Cr: ≤1 mg/kg, Cu: ≤1 mg/kg, Fe: ≤5 mg/kg, K: ≤5 mg/kg, Mg: ≤5 mg/kg, Mn: ≤0.5 mg/kg, Na: ≤20 mg/kg, Ni: ≤1 mg/kg, Pb: ≤1 mg/kg, Sb: ≤2 mg/kg, Zn: ≤2 mg/kg

suitability

passes test for appearance of solution

greener alternative category

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Other Notes

El ácido fosfórico concentrado es aproximadamente H3PO4 (acuoso) al 85%.
The article number 30417-4X2.5L will be discontinued. Please order the single bottle 30417-2.5L which is physically identical with the same exact specifications.
The article number 30417-4X2.5L-M will be discontinued. Please order the single bottle 30417-2.5L-M which is physically identical with the same exact specifications.
The article number 30417-6X1L will be discontinued. Please order the single bottle 30417-1L which is physically identical with the same exact specifications.
The article number 30417-6X1L-M will be discontinued. Please order the single bottle 30417-1L-M which is physically identical with the same exact specifications.

Application


  • Cooperative Rh/Achiral Phosphoric Acid-Enabled [3+3] Cycloannulation of Carbonyl Ylides with Quinone Monoimines: Synthesis of Benzofused Dioxabicyclo[3.2.1]octane Scaffolds.: This study demonstrates the catalytic role of phosphoric acid in a [3+3] cycloannulation reaction, enabling the efficient synthesis of complex organic scaffolds (Tu et al., 2024).

General description

We are committed to bringing you Greener Alternative Products, which belong to one of the four categories of greener alternatives. Phosphoric acid-doped polybenzimidazole (PBI) membranes offer a cleaner path to energy by enabling high-temperature fuel cells that efficiently convert hydrogen into electricity with low emissions. Their durability and proton conductivity make them ideal for sustainable power systems. Click here for more information.

pictograms

CorrosionExclamation mark

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Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

Clase de almacenamiento

8A - Combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


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Internal versus external surface active sites in ZSM-5 zeolite: Part 1. Fries rearrangement catalyzed by modified and unmodified H3PO4/ZSM-5.
Ghiaci M, et al.
Applied Catalysis A: General, 298, 32-39 (2006)
D S Marinier et al.
Journal of lipid research, 29(9), 1237-1243 (1988-09-01)
In order to study the lipid composition of human white matter, we have developed a 31P NMR spectroscopy method, which allows the determination and quantitation of the main phospholipids found in biological membranes. The technique is based upon the use
P Meneses et al.
Journal of lipid research, 29(5), 679-689 (1988-05-01)
The common phospholipids from biological sources were quantitated using phosphorus-31 nuclear magnetic resonance (NMR) spectroscopy in conjunction with an analytical reagent composed of two parts: 1) 2 ml of reagent chloroform in which was dissolved 0.01-100 mg of crude tissue
J M Fujitaki et al.
Biochemistry, 20(12), 3658-3664 (1981-06-09)
Phosphorus-31 nuclear magnetic resonance (31P NMR) is used to investigate acid-labile phosphorylation of histone H4. 31P NMR detects phosphorylated histidine residues in in vitro enzymatically phosphorylated H4. The source of kinase is nuclei from either regenerating rat liver or Walker-256
Alessio Ciulli et al.
Journal of medicinal chemistry, 49(16), 4992-5000 (2006-08-04)
Mapping interactions at protein-ligand binding sites is an important aspect of understanding many biological reactions and a key part of drug design. In this paper, we have used a fragment-based approach to probe "hot spots" at the cofactor-binding site of

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