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Merck

1.11670

Formic acid

greener alternative

98-100% Suprapur®

Synonym(s):

Formic acid, Methanoic acid, Formylic acid

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About This Item

Linear Formula:
HCOOH
CAS Number:
Molecular Weight:
46.03
EC Index Number:
200-579-1
UNSPSC Code:
12352106
Beilstein/REAXYS Number:
1209246
MDL number:
Assay:
≥98% (acidimetric), 98-100%
Concentration:
≤100% in formic acid
Form:
liquid
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Product Name

Formic acid 98-100%, Suprapur®

SMILES string

OC=O

InChI

1S/CH2O2/c2-1-3/h1H,(H,2,3)

InChI key

BDAGIHXWWSANSR-UHFFFAOYSA-N

assay

≥98% (acidimetric), 98-100%

form

liquid

autoignition temp.

1004 °F

expl. lim.

12-38 % (v/v), 57 %

Quality Level

vapor density

1.6 (vs air)

vapor pressure

44.8 mmHg ( 20 °C)

description

for inorganic trace analysis

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

concentration

≤100% in formic acid

technique(s)

mass spectrometry (MS): suitable

refractive index

n20/D 1.370 (lit.)

pH

2.2 (20 °C, 10 g/L in H2O)

bp

100-101 °C (lit.), 101 °C/1013 hPa

mp

8.2-8.4 °C (lit.)

transition temp

flash point 49.5 °C

solubility

soluble (Water: miscible in all proportions)

density

1.22 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤1000 ppb, phosphate, phosphite (as PO43-): ≤100 ppb, sulfate, sulfite (as SO42-): ≤500 ppb

cation traces

Ag: ≤0.5 ppb, Al: ≤5 ppb, As: ≤1 ppb, Au: ≤0.5 ppb, Ba: ≤1 ppb, Be: ≤0.5 ppb, Bi: ≤0.5 ppb, Ca: ≤10 ppb, Cd: ≤0.5 ppb, Co: ≤0.5 ppb, Cr: ≤1 ppb, Cu: ≤1 ppb, Fe: ≤5 ppb, Ga: ≤0.5 ppb, Ge: ≤0.5 ppb, Hg: ≤1 ppb, In: ≤0.5 ppb, K: ≤5 ppb, Li: ≤0.5 ppb, Mg: ≤2 ppb, Mn: ≤0.5 ppb, Mo: ≤0.5 ppb, Na: ≤5 ppb, Ni: ≤1 ppb, Pb: ≤1 ppb, Pd: ≤1 ppb, Pt: ≤1 ppb, Sb: ≤1 ppb, Sn: ≤0.5 ppb, Sr: ≤0.5 ppb, Ti: ≤0.5 ppb, Tl: ≤0.5 ppb, U: ≤0.5 ppb, V: ≤0.5 ppb, Zn: ≤5 ppb, Zr: ≤0.5 ppb

greener alternative category

storage temp.

2-30°C

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Application


  • Identification of in vivo metabolites of Citri Sarcodactylis Fructus by UHPLC-Q/Orbitrap HRMS.: This study used advanced chromatographic techniques to identify and analyze metabolites, demonstrating the application of formic acid in enhancing detection sensitivity and accuracy in analytical chemistry (Deng et al., 2023).

  • Phosphorus recovery from aqueous product of hydrothermal carbonization of cow manure.: Research explored the recovery of phosphorus from hydrothermally carbonized cow manure, where formic acid played a crucial role in the chemical analysis and enhancement of recovery processes (Qaramaleki et al., 2023).

  • Identification and quality evaluation of Chinese rice wine using UPLC-PDA-QTOF/MS with dual-column separation.: Demonstrates formic acid′s role in optimizing the chromatographic profiles of complex organic compounds in beverages, thereby aiding in their quality assessment and standardization (Xiang et al., 2023).

Legal Information

SUPRAPUR is a registered trademark of Merck KGaA, Darmstadt, Germany

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalysis. Click here for more information.

Other Notes

Replaces: 11670-1; 11670

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1A

supp_hazards

Storage Class

3 - Flammable liquids

wgk

WGK 1

flash_point_f

121.1 °F - closed cup

flash_point_c

49.5 °C - closed cup


Certificates of Analysis (COA)

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