694975
o-Phenylenediamine
sublimed, ≥99%
Synonym(s):
1,2-Diaminobenzene, 1,2-Phenylenediamine, OPD
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About This Item
Empirical Formula (Hill Notation):
C6H8N2
CAS Number:
Molecular Weight:
108.14
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
202-430-6
Beilstein/REAXYS Number:
606074
MDL number:
Assay:
≥99%
Form:
sublimed
vapor density
3.7 (vs air)
Quality Level
vapor pressure
0.01 mmHg ( 25 °C)
assay
≥99%
form
sublimed
bp
256-258 °C
mp
100-102 °C
SMILES string
Nc1ccccc1N
InChI
1S/C6H8N2/c7-5-3-1-2-4-6(5)8/h1-4H,7-8H2
InChI key
GEYOCULIXLDCMW-UHFFFAOYSA-N
Application
o-Phenylenediamine can be used in the synthesis of:
- Various benzimidazole derivatives that are structural units of several bioactive drug substances and pigments.
- N-doped colloidal graphene quantum dots (QDs), which can electrochemically catalyze the oxygen reduction reactions.
- N-doped graphene nanoplatelets from simple solution edge-functionalization for n-type field-effect transistors.
- N-heteroacenes (azaacenes) that are good candidates as active materials for organic thin film transistors.
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Danger
Hazard Classifications
Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Eye Irrit. 2 - Muta. 2 - Skin Sens. 1
Storage Class
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
276.8 °F - closed cup
flash_point_c
136 °C - closed cup
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Mild and highly efficient method for the synthesis of 2-arylbenzimidazoles and 2-arylbenzothiazoles.
Bahrami K, et al.
The Journal of Organic Chemistry, 73(17), 6835-6837 (2008)
Extension of N?Heteroacenes through a Four?Membered Ring.
Yang S, et al.
Chemistry?A European Journal, 22(19), 6637-6642 (2016)
Nitrogen-doped graphene nanoplatelets from simple solution edge-functionalization for n-type field-effect transistors.
Chang DW, et al.
Journal of the American Chemical Society, 135(24), 8981-8988 (2013)