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Merck

244759

Titanium(IV) ethoxide

greener alternative

technical grade

Synonym(s):

Tetraethyl orthotitanate, Tetraethyl titanate

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About This Item

Linear Formula:
Ti(OC2H5)4
CAS Number:
Molecular Weight:
228.11
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3678992
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grade

technical grade

Quality Segment

form

liquid

composition

Ti, 19.0-21.0% gravimetric

reaction suitability

core: titanium, reagent type: catalyst

greener alternative product characteristics

Design for Energy Efficiency
Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product, Greener Alternative Product

impurities

~20% Tetraisopropyl orthotitanate

refractive index

n20/D 1.505 (lit.)

bp

150-152 °C/10 mmHg (lit.)

density

1.088 g/mL at 25 °C (lit.)

greener alternative category

SMILES string

CCO[Ti](OCC)(OCC)OCC

InChI

1S/4C2H5O.Ti/c4*1-2-3;/h4*2H2,1H3;/q4*-1;+4

InChI key

JMXKSZRRTHPKDL-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This is an enabling product and can be used as a precursor to make perovskite oxides, which promote thermoelectric heat-to-electricity conversion, improving energy efficiency. Click here for more information.

Application

Titanium ethoxide is used widely as a precursor for the synthesis of Ti4+ ions titania nanoparticles by various techniques such as :
  • in the sol-gel synthesis of free-standing ferroelectric lead zirconate titanate nanoparticles
  • spherical titania cores, produced either by hydrolysis of Ti(IV) ethoxide droplets in contact with water vapor or
  • by preadsorption of the titanium alkoxides into/onto the clay mineral platelets and their subsequent hydrolysis and calcination.


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Warning

hcodes

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

107.6 °F - closed cup

flash_point_c

42 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter



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