34869
Dimethyl sulfoxide
suitable for HPLC, ≥99.7%
Synonym(s):
DMSO
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About This Item
Linear Formula:
(CH3)2SO
CAS Number:
Molecular Weight:
78.13
UNSPSC Code:
41116105
NACRES:
NA.21
PubChem Substance ID:
EC Number:
200-664-3
Beilstein/REAXYS Number:
506008
MDL number:
Assay:
≥99.7%
Grade:
HPLC grade
Technique(s):
HPLC: suitable
Vapor pressure:
0.42 mmHg ( 20 °C)
InChI key
IAZDPXIOMUYVGZ-UHFFFAOYSA-N
InChI
1S/C2H6OS/c1-4(2)3/h1-2H3
SMILES string
CS(C)=O
grade
HPLC grade
Quality Level
vapor pressure
0.42 mmHg ( 20 °C)
assay
≥99.7%
form
liquid
autoignition temp.
573 °F
expl. lim.
42 %, 63 °F
technique(s)
HPLC: suitable
impurities
≤0.002% non-volatile matter, ≤0.2% water (Karl Fischer)
transmittance
270 nm, ≥20%, 280 nm, ≥50%, 300 nm, ≥80%, 350 nm, ≥98%
density
1.10 g/mL (lit.)
application(s)
food and beverages
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General description
Dimethyl sulfoxide (DMSO) is a polar organic solvent. DMSO activated by various electrophiles (oxalyl chloride) has been used to oxidize various alcohols (primary, secondary, allylic, benzylic, hindered and bicyclic). Carbonyl compounds are formed as reaction products. Due to its higher stability, it has been proposed as an alternate solvent for methyl cellosolve for use in ninhydrin reaction.
Application
Suitable for HPLC, spectrophotometry, environmental testing
Other Notes
Important notice
- The article number 34869-4X2.5L will be discontinued. Please order the single bottle 34869-2.5L which is physically identical with the same exact specifications.
- The article number 34869-6X1L will be discontinued. Please order the single bottle 34869-1L which is physically identical with the same exact specifications.
For information on dimethyl sulfoxide miscibility, please visit the following link:
Dimethyl Sulfoxide Miscibility/Immiscibility Table
Dimethyl Sulfoxide Miscibility/Immiscibility Table
Disclaimer
Supercools easily and remelts slowly at room temperature. Solidified product can be re-liquified by warming to room temperature without detriment to the product.
Storage Class
10 - Combustible liquids
wgk
WGK 1
flash_point_f
188.6 °F - closed cup
flash_point_c
87 °C - closed cup
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A RAPID PERMETHYLATION OF GLYCOLIPID, AND POLYSACCHARIDE CATALYZED BY METHYLSULFINYL CARBANION IN DIMETHYL SULFOXIDE.
S HAKOMORI
Journal of biochemistry, 55, 205-208 (1964-02-01)
Oxidation of alcohols by ?activated? dimethyl sulfoxide. A preparative, steric and mechanistic study.
Omura K and Swern D.
Tetrahedron, 34(11), 1651-1660 (1978)
Amino acid analysis: aqueous dimethyl sulfoxide as solvent for the ninhydrin reaction.
S Moore
The Journal of biological chemistry, 243(23), 6281-6283 (1968-12-10)
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