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222380

Allylpalladium(II) chloride dimer

98%, solid

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Synonym(s):

Bis((η3-allyl)(chloro)palladium), Di-ο-allyldi-μ-chlorodipalladium, [PdCl(C3H5)]2

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About This Item

Empirical Formula (Hill Notation):
C6H10Cl2Pd2
CAS Number:
12012-95-2
Molecular Weight:
365.89
NACRES:
NA.22
PubChem Substance ID:
24853328
UNSPSC Code:
12161600
EC Number:
234-579-8
Beilstein/REAXYS Number:
4124623
MDL number:
MFCD00044874
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Product Name

Allylpalladium(II) chloride dimer, 98%

Quality Segment

assay

98%

form

solid

reaction suitability

core: palladium, reaction type: Cross Couplings, reagent type: catalyst
reaction type: C-H Activation

greener alternative product characteristics

Catalysis
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storage temp.

2-8°C

SMILES string

Cl[Pd]CC=C.Cl[Pd]CC=C

InChI

1S/2C3H5.2ClH.2Pd/c2*1-3-2;;;;/h2*3H,1-2H2;2*1H;;/q;;;;2*+1/p-2

InChI key

TWKVUTXHANJYGH-UHFFFAOYSA-L

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
Allylpalladium(II) chloride dimer is employed as catalyst in Heck reaction. It also participates as catalyst in the tandem nucleophilic allylation-alkoxyallylation reaction of the alkynylaldehydes with allyl chloride and allyltributylstannane.

Application

Application Guide for Palladium Catalyzed Cross-Coupling Reactions
Allylpalladium(II) chloride dimer has been employed for the following studies:
  • Synthesis of cationic palladium cataysts, used in the microwave-assisted Heck arylation.
  • Synthesis of N-heterocyclic carbene-palladium-η3-allyl chloride complexes, which are efficient catalyst for the Suzuki-Miyaura cross-coupling of aryl bromides and activated aryl chlorides.
  • Synthesis of 1,4-diallyl-1,2-dihydroisoquinolines.
  • As catalyst for greener Buchwald-Hartwig coupling in TPGS-750-M.

On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors

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Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Codes

H315

Hazard Classifications

Skin Irrit. 2

Storage Class

11 - Combustible Solids

PPE (personal protective equipment)

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

222380-BULK: + 222380-5G: + 222380-500MG: + 222380-10G: + 222380-100MG: + 222380-5MG-KC: + 222380-1G: + 222380-VAR:

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