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Merck

244759

Titanium(IV) ethoxide

technical grade

Synonym(s):

Tetraethyl orthotitanate, Tetraethyl titanate

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About This Item

Linear Formula:
Ti(OC2H5)4
CAS Number:
Molecular Weight:
228.11
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3678992
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grade

technical grade

Quality Level

form

liquid

composition

Ti, 19.0-21.0% gravimetric

reaction suitability

core: titanium, reagent type: catalyst

impurities

~20% Tetraisopropyl orthotitanate

refractive index

n20/D 1.505 (lit.)

bp

150-152 °C/10 mmHg (lit.)

density

1.088 g/mL at 25 °C (lit.)

SMILES string

CCO[Ti](OCC)(OCC)OCC

InChI

1S/4C2H5O.Ti/c4*1-2-3;/h4*2H2,1H3;/q4*-1;+4

InChI key

JMXKSZRRTHPKDL-UHFFFAOYSA-N

Application

Titanium ethoxide is used widely as a precursor for the synthesis of Ti4+ ions titania nanoparticles by various techniques such as :
  • in the sol-gel synthesis of free-standing ferroelectric lead zirconate titanate nanoparticles
  • spherical titania cores, produced either by hydrolysis of Ti(IV) ethoxide droplets in contact with water vapor or
  • by preadsorption of the titanium alkoxides into/onto the clay mineral platelets and their subsequent hydrolysis and calcination.


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pictograms

FlameExclamation mark

signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

107.6 °F - closed cup

flash_point_c

42 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Group 4: Flammable liquids + Type 2 petroleums + Hazardous rank III + Water insoluble liquid

fsl



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Articles

エアロゲル構造体の超低密度メソポーラス酸化物を水素貯蔵材料として用いた事例を紹介します。

ペロブスカイト型酸化物や関連物質は、その柔軟性の高さから、新たな熱電材料の探索や最適化に関する非常に大きな可能性を持っています。

ナノワイヤは、ナノスケールの電子的および構造的制御によってバルク材料の限界を克服し、次世代デバイスや応用の実現に貢献することが期待されています。

View All Articles

Preparation and characterization of clay mineral intercalated titanium dioxide nanoparticles
Mogyorosi K, et al.
Langmuir, 19(7), 2938-2946 (2003)
Preparation of uniform spherical titania particles coated with polyurea by the aerosol technique.
Mayville FC, et al.
Journal of Colloid and Interface Science, 120(1), 135-139 (1987)
Two-photon polymerization of metal ions doped acrylate monomers and oligomers for three-dimensional structure fabrication
Duan XM, et al.
Thin Solid Films, 453, 518-521 (2004)