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Merck

254770

Potassium ethyl xanthogenate

96%

Synonym(s):

O-Ethylxanthic acid potassium salt, KEX, Potassium O-ethyl dithiocarbonate, Potassium xanthogenate

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About This Item

Linear Formula:
C2H5OCSSK
CAS Number:
140-89-6
Molecular Weight:
160.30
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24855406
EC Number:
205-439-3
Beilstein/REAXYS Number:
3596974
MDL number:
MFCD00004931
Assay:
96%
Form:
powder

Key Documents

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Quality Level

100

assay

96%

form

powder

mp

210 °C (dec.) (lit.)

solubility

alcohol: soluble(lit.), water: very soluble(lit.)

SMILES string

[K+].CCOC([S-])=S

InChI

1S/C3H6OS2.K/c1-2-4-3(5)6;/h2H2,1H3,(H,5,6);/q;+1/p-1

InChI key

JCBJVAJGLKENNC-UHFFFAOYSA-M

Related Categories

Application

Potassium ethyl xanthogenate (ethyl potassium xanthogenate) has been used:
  • in synthesis of unsymmetrical sulfides via cross-coupling reaction, using recyclable CuO nanoparticles under ligand-free conditions
  • as surfactant to investigate the adsorption of colloidal dye Disperse Blue 3 onto pretreated polyester fabric
  • in determination of microgram amounts of cadmium in water samples by substoichiometric radiochemical method

pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

supp_hazards

EUH018

Storage Class

4.2 - Pyrophoric and self-heating hazardous materials

wgk

WGK 3

flash_point_f

204.8 °F

flash_point_c

96 °C

ppe

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

254770-BULK: + 254770-500G: + 254770-VAR: + 254770-100G: + 254770-25KG: + 254770-5G:

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Certificates of Analysis (COA)

Lot/Batch Number
S44170
S39143
06219LE
S37598
03327HE

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J Gottofrey et al.
Pharmacology & toxicology, 63(1), 46-51 (1988-07-01)
Brown trouts, Salmo trutta, were exposed to water containing 0.1 or 10 micrograms/l of 63Ni2+, alone or with potassium ethylxanthate or sodium diethyldithiocarbamate. After one and three weeks the accumulation and disposition of the 63Ni2+ in the fish were examined
Yi-Kuo Chang et al.
Journal of hazardous materials, 94(1), 89-99 (2002-07-27)
Although, the xanthate process has been shown to be an effective method for heavy metal removal from contaminated water, a heavy metal contaminated residual sludge is produced by the treatment process and the metal-xanthate sludge must be handled in accordance
M Espinosa-Jiménez et al.
Journal of colloid and interface science, 265(2), 227-233 (2003-09-10)
Data are presented on the adsorption of the colloidal dye Disperse Blue 3 onto polyester fabric (Dacron 54, Stile 777), the fabric being pretreated with different amounts of the surfactant potassium ethyl xanthogenate (PEX). This study has been made by
D J C Prasad et al.
Organic letters, 13(5), 1008-1011 (2011-01-29)
An efficient Cu-catalyzed one-pot approach for the synthesis of unsymmetrical diaryl thioethers using potassium ethyl xanthogenate as a thiol surrogate is developed. This new protocol avoids usage of intricate thiols and makes use of its easily available xanthate as a
Amiel Boullemant et al.
Environmental science & technology, 43(9), 3308-3314 (2009-06-19)
Cadmium forms neutral, lipophilic Cd(L)2(0) complexes with diethyldithiocarbamate (DDC) and with ethylxanthate (XANT). Uptake of these complexes bythree unicellularfreshwater green algae (Chlamydomonas reinhardtii, Chlorella fusca, and Pseudokirchneriella subcapitata) was determined at two pH values (7.0 and 5.5) and compared to
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