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Merck

327182

tert-Butyl acrylate

contains 10-20 ppm monomethyl ether hydroquinone as inhibitor, 98%

Synonym(s):

t-Butyl acrylate

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About This Item

Linear Formula:
CH2=CHCOOC(CH3)3
CAS Number:
1663-39-4
Molecular Weight:
128.17
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
24859647
EC Number:
216-768-7
Beilstein/REAXYS Number:
1742329
MDL number:
MFCD00008809

Key Documents

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InChI key

ISXSCDLOGDJUNJ-UHFFFAOYSA-N

InChI

1S/C7H12O2/c1-5-6(8)9-7(2,3)4/h5H,1H2,2-4H3

SMILES string

CC(C)(C)OC(=O)C=C

assay

98%

form

liquid

contains

10-20 ppm monomethyl ether hydroquinone as inhibitor

Quality Level

200

bp

61-63 °C/60 mmHg (lit.)

density

0.875 g/mL at 25 °C (lit.)

Related Categories

General description

tert-Butyl acrylate is an organic chemical compound that can be used as a monomer for the preparation of various types of polymers with desirable characteristics. It can undergo free-radical polymerization, which is a common method used to produce polymeric materials. Additionally, tert-butyl acrylate polymers can be copolymerized with other monomers to modify their properties. The versatility of tert-butyl acrylate makes it suitable for a wide range of applications, including coatings, adhesives, sealants, elastomers, and specialty films.

Application

tert-Butyl acrylate is a monomer used to produce poly(tert-butyl acrylate) (PtBA) polymers and copolymers, and poly(acrylic acid) polyelectrolyte brushes. It undergoes radiation polymerization to form TBA-gels for radio-fluorogenic dose imaging applications. The monomer can be used to synthesize Poly(t-butyl acrylate). It may be used as a reactive diluent in a study.

tert-Butyl acrylate can also be used as:
  • A building block in the synthesis of asymmetric membranes, which are potentially useful in filtration, separation, or gas permeation processes.
  • A monomer in the preparation of a siloxane-incorporated copolymer binder for silicon anodes in lithium-ion batteries.
  • A monomer in the synthesis of poly(tert-butyl acrylate)/carbon nanofiber (CNF) materials through atom transfer radical polymerization (ATRP).

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Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Flam. Liq. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 2

flash_point_f

62.6 °F - closed cup

flash_point_c

17 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Group 4: Flammable liquids + Type 1 petroleums + Hazardous rank II + Water insoluble liquid

fsl

Substances Subject to be Indicated Names

ishl_indicated

Substances Subject to be Notified Names

ishl_notified

327182-VAR: + 327182-BULK: + 327182-100ML: + 327182-5ML: + 327182-1L:

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Certificates of Analysis (COA)

Lot/Batch Number
MKCN0605
MKCL5121
MKCJ8234
STBH8256
SHBJ8968

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Huanhuan Liu et al.
Polymers, 11(5) (2019-05-10)
Gambogenic acid (GNA) has been demonstrated with outstanding antitumor activity as a potential antitumor drug in recent years. However, the low solubility and deficient bioavailability of GNA seriously hinder its practical application in the clinic area. In this study, a
Study of the kinetics of step and flash imprint lithography photopolymerization.
Dickey MD, et al.
AIChE Journal, 51(9), 2547-2555 (2005)
Polymer-gel formation and reformation on irradiation of tertiary-butyl acrylate
Yao T, et al.
Radiation Physics and Chemistry, 97, 147-152 (2014)
Block Copolymer Synthesis Using a Commercially Available Nitroxide-Mediated Radical Polymerization (NMP) Initiator
Lee NS and Wooley KL
Material Matters, 5(1), 9-9 (2010)
Daniel Hassan et al.
Pharmaceutics, 12(11) (2020-11-19)
Globally, human beings continue to be at high risk of infectious diseases caused by methicillin-resistant Staphylococcus aureus (MRSA); and current treatments are being depleted due to antimicrobial resistance. Therefore, the synthesis and formulation of novel materials is essential for combating
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