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Merck

380547

4-Acetoxystyrene

96%, contains 200-300 ppm monomethyl ether hydroquinone as inhibitor

Synonym(s):

4-Ethenylphenol acetate, 4-Vinylphenyl acetate

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About This Item

Linear Formula:
CH3CO2C6H4CH=CH2
CAS Number:
Molecular Weight:
162.19
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12162002
MDL number:
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InChI

1S/C10H10O2/c1-3-9-4-6-10(7-5-9)12-8(2)11/h3-7H,1H2,2H3

SMILES string

CC(=O)Oc1ccc(C=C)cc1

InChI key

JAMNSIXSLVPNLC-UHFFFAOYSA-N

assay

96%

form

liquid

contains

200-300 ppm monomethyl ether hydroquinone as inhibitor

refractive index

n20/D 1.538 (lit.)

viscosity

4.2 cP(25 °C, Brookfield)(lit.)

bp

260 °C (lit.)

mp

7-8 °C (lit.)

density

1.06 g/mL at 25 °C (lit.)

storage temp.

2-8°C

Quality Level

Application

Polymer used in microlithography. Precursor to p-hydroxystyrene that is readily derivatized.

Biochem/physiol Actions

Reactivity ratio: 4-Acetoxystyrene/styrene 1.02/0.80
4-Acetoxystyrene/methyl methacrylate 0.76/0.88
4-Acetoxystyrene/maleic anhydride 0/0

Features and Benefits

Undergoes free radical polymerization, similar to styrene

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1

Storage Class

10 - Combustible liquids

wgk

WGK 2

flash_point_f

190.4 °F - closed cup

flash_point_c

88 °C - closed cup


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Group 4: Flammable liquids + Type 3 petroleums + Hazardous rank III + Water insoluble liquid

fsl

380547-VAR: + 380547-5ML: + 380547-BULK: + 380547-25ML: + 380547-700ML:

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Articles

ニトロキシドを介したラジカル重合(NMP)の概略とNMP開始剤について、実際のプロトコルを中心にご紹介します。

Block copolymer synthesis using a commercially available nitroxide-mediated radical polymerization (NMP) initiator

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