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407275

N,N-Dimethylaniline

purified by redistillation, ≥99.5%

Synonym(s):

N,N-Dimethylaniline, N,N-Dimethylphenylamine, DMA, Dimethylaniline, Dimethylphenylamine

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About This Item

Linear Formula:
C6H5N(CH3)2
CAS Number:
121-69-7
Molecular Weight:
121.18
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24865440
EC Number:
204-493-5
Beilstein/REAXYS Number:
507140
MDL number:
MFCD00008304
Assay:
≥99.5%
Bp:
193-194 °C (lit.)
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Quality Level

200

assay

≥99.5%

form

liquid

purified by

glass distillation, redistillation

refractive index

n20/D 1.557 (lit.)

pH

7.4 (20 °C, 1.2 g/L)

bp

193-194 °C (lit.)

mp

1.5-2.5 °C (lit.)

density

0.956 g/mL at 25 °C (lit.)

functional group

amine

SMILES string

CN(C)c1ccccc1

InChI

1S/C8H11N/c1-9(2)8-6-4-3-5-7-8/h3-7H,1-2H3

InChI key

JLTDJTHDQAWBAV-UHFFFAOYSA-N

General description

Anodic oxidation of N,N-dimethylaniline at platinum electrode in acidic buffers has been studied by conventional and cyclic voltammetry. Photoreduction of excited benzophenone (BP) by DMA in acetonitrile solution has been investigated by picosecond-femtosecond laser photolysis and time resolved transient absorption spectroscopy.

Application

N,N-Dimethylaniline (DMA) may be used for the preparation of poly(N,N-dimethylaniline) film by anodic oxidation of DMA.

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Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 2 - Carc. 2

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

167.0 °F - closed cup

flash_point_c

75 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Class II Designated Chemical Substances

prtr

Group 4: Flammable liquids + Type 3 petroleums + Hazardous rank III + Water insoluble liquid

fsl

Substances Subject to be Indicated Names

ishl_indicated

Substances Subject to be Notified Names

ishl_notified

407275-800ML:4.548173940274E12 + 407275-100ML:4.548173940267E12

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Certificates of Analysis (COA)

Lot/Batch Number
44696EJ
16329HH
27901KI
17111AE
08130AC

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Electrochemically polymerized N, N-dimethylaniline film with ion-exchange properties as an electrode modifier.
Oyama N, et al.
Analytical Chemistry, 57(8), 1526-1532 (1985)
Femtosecond-picosecond laser photolysis studies on photoreduction process of excited benzophenone with N,N-dimethylaniline in acetonitrile solution.
Miyasaka H, et al.
Bulletin of the Chemical Society of Japan, 63(12), 3385-3397 (1990)
Anodic oxidation studies of N,N-dimethylaniline. I. Voltammetric and spectroscopic investigations at platinum electrodes.
Mizoguchi T and Adams RN.
Journal of the American Chemical Society, 84(11), 2058-2061 (1962)
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