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Merck

459097

Copper(II) chloride dihydrate

99.999%

Synonym(s):

Cupric chloride dihydrate

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About This Item

Linear Formula:
CuCl2 · 2H2O
CAS Number:
10125-13-0
Molecular Weight:
170.48
NACRES:
NA.23
PubChem Substance ID:
24869509
UNSPSC Code:
12352302
EC Number:
231-210-2
MDL number:
MFCD00149674
Assay:
99.999%
Form:
solid

Key Documents

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Product Name

Copper(II) chloride dihydrate, 99.999%

InChI key

MPTQRFCYZCXJFQ-UHFFFAOYSA-L

InChI

1S/2ClH.Cu.2H2O/h2*1H;;2*1H2/q;;+2;;/p-2

SMILES string

Cl[Cu]Cl.[H]O[H].[H]O[H]

vapor density

>1 (vs air)

assay

99.999%

form

solid

reaction suitability

core: copper

impurities

≤15.0 ppm Trace Metal Analysis

mp

100 °C (dec.) (lit.)

Quality Level

100

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Application

Copper chloride dehydrate refluxed in acetonitrile can chemoselectively hydrolyze semicarbazones to carbonyl compounds. Copper chloride dehydrate may be used as a catalyst for efficiently cleaving t-butyldimethylsilyl (TBDMS).

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Eye Dam. 1 - Skin Irrit. 2

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Deleterious substance

pdsc

Class I Designated Chemical Substances

prtr

Substances Subject to be Indicated Names

ishl_indicated

Substances Subject to be Notified Names

ishl_notified

459097-5G:4548173154374 + 459097-25G:4548173154367 + 459097-BULK: + 459097-VAR:

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Certificates of Analysis (COA)

Lot/Batch Number
MKCQ6520
MKCP2673
MKCN1547
MKCK5198
MKCD4961

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Deprotection of t-butyldimethylsiloxy (TBDMS) protecting group with catalytic copper (II) chloride dihydrate.
Ping Z, et al.
Chinese Chemical Letters = Zhongguo Hua Xue Kuai Bao, 11(19), 753-756 (2000)
Regeneration of carbonyl compounds from semicarbazones by copper (II) chloride dihydrate.
Ram RN and Varsha K.
Tetrahedron Letters, 32(41), 5829-5832 (1991)
María S Islas et al.
Inorganic chemistry, 53(11), 5724-5737 (2014-05-16)
A new Cu(II) complex with the antihypertensive drug telmisartan, [Cu8Tlm16]·24H2O (CuTlm), was synthesized and characterized by elemental analysis and electronic, FTIR, Raman and electron paramagnetic resonance spectroscopy. The crystal structure (at 120 K) was solved by X-ray diffraction methods. The
Sebastian Müller et al.
PloS one, 13(11), e0206764-e0206764 (2018-11-07)
The clinically approved drug metformin has been shown to selectively kill persister cancer cells through mechanisms that are not fully understood. To provide further mechanistic insights, we developed a drug surrogate that phenocopies metformin and can be labeled in situ
Su-Jeong Kim et al.
Free radical biology & medicine, 53(4), 936-950 (2012-06-12)
Loss-of-function mutations in the PARK7/DJ-1 gene cause early onset autosomal-recessive Parkinson disease. DJ-1 has been implicated in protection of neurons from oxidative stress and in regulation of transcriptional activity. However, whether there is a relationship between the subcellular localization of
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