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Merck

634875

Aluminum oxide

greener alternative

single crystal substrate, <0001>

Synonym(s):

Sapphire, Alumina

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About This Item

Linear Formula:
Al2O3
CAS Number:
1344-28-1
Molecular Weight:
101.96
PubChem Substance ID:
24882698
eCl@ss:
38120402
UNSPSC Code:
12352303
NACRES:
NA.23
EC Number:
215-691-6
MDL number:
MFCD00003424

Key Documents

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InChI key

TWNQGVIAIRXVLR-UHFFFAOYSA-N

InChI

1S/2Al.3O

SMILES string

O=[Al]O[Al]=O

description

Crystallographic D spacing ((0001) - c plane: 2.165 Angstrom), Crystallographic D spacing ((1011) - s plane: 1.961 Angstrom), Crystallographic D spacing ((1040) - m plane: 1.375 Angstrom), Crystallographic D spacing ((1102) - r plane: 1.740 Angstrom), Crystallographic D spacing ((1120) - a plane: 2.379 Angstrom), Crystallographic D spacing ((1123) - n plane: 1.147 Angstrom), single side polished

form

single crystal substrate

hardness

9 mohs

Quality Level

100

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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L × W × thickness

10 mm × 10 mm × 0.5 mm

mp

2040 °C (lit.)

greener alternative category

Enabling

semiconductor properties

<0001>

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General description

We are committed to bringing you Greener Alternative Products, which belong to one of the four categories of greener alternatives. Aluminum oxide serves as a multifunctional additive or coating in lithium-ion batteries, helping stabilize electrode–electrolyte interfaces, suppress side reactions, improve thermal stability, and extend cycle life. By enabling safer, longer-lasting cells, it reduces material waste and energy use across the battery lifecycle. Click here for more information.
thermal expansion = 7.5 × 10-6 /°C; specific heat = 0.10 cal/°C; thermal conductivity = 46.06 @ 0 °C, 25.12 @ 100 °C, 12.56 @ 400 °C (W/m,K); dielectric constant = ~9.4 @ 300 K at A axis, ~11.58 @ C axis; loss tangent at 10 GHz < 2 × 10-5 at A axis, 5 × 10-6 at C axis

Features and Benefits

Common substrate for III-V nitrides as well as many other epitaxial films.

Physical form

Crystalline, hexagonal (a = 4.758 Å, c = 12.992)

Storage Class

13 - Non Combustible Solids

wgk

nwg

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

634875-5EA: + 634875-BULK: + 634875-1EA: + 634875-VAR:

jan

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Certificates of Analysis (COA)

Lot/Batch Number
MKCL0052
MKCJ8563
MKCG7943
MKCF9404
MKCD1697

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G Siddiqi et al.
Dalton transactions (Cambridge, England : 2003), 44(32), 14349-14353 (2015-07-23)
A simple one-step and gram-scale synthesis of [Au5Mes5] from AuCl3 was developed, and this molecular precursor was used to generate Au nanoparticles on SiO2 and Al2O3. While [Au5Mes5] does not react with surface silanols and is only physisorbed, its incipient
Joohoon Kang et al.
ACS nano, 9(4), 3596-3604 (2015-03-19)
Solution dispersions of two-dimensional (2D) black phosphorus (BP)--often referred to as phosphorene--are achieved by solvent exfoliation. These pristine, electronic-grade BP dispersions are produced with anhydrous organic solvents in a sealed-tip ultrasonication system, which circumvents BP degradation that would otherwise occur
Chien-Chih Lin et al.
Nanoscale, 5(17), 8090-8097 (2013-07-25)
We demonstrated a promising route for enhancing temperature sensitivity, improving saturation voltage, and reducing power consumption of the MOS(p) tunneling temperature sensors by introducing ultrathin Al2O3 into the dielectric stacks. Detailed illustrations of the working mechanism and device concept are
Jaakko Akola et al.
Proceedings of the National Academy of Sciences of the United States of America, 110(25), 10129-10134 (2013-06-01)
Glass formation in the CaO-Al2O3 system represents an important phenomenon because it does not contain typical network-forming cations. We have produced structural models of CaO-Al2O3 glasses using combined density functional theory-reverse Monte Carlo simulations and obtained structures that reproduce experiments
Colin J Ingham et al.
Biotechnology advances, 30(5), 1089-1099 (2011-08-23)
Porous aluminum oxide (PAO) is a ceramic formed by an anodization process of pure aluminum that enables the controllable assembly of exceptionally dense and regular nanopores in a planar membrane. As a consequence, PAO has a high porosity, nanopores with
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