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Merck

643645

Silica, mesostructured

MCM-41 type (hexagonal)

Synonym(s):

Silica, Silicon dioxide

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About This Item

Linear Formula:
SiO2
CAS Number:
Molecular Weight:
60.08
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
EC Number:
231-545-4
MDL number:
Technical Service
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Quality Level

form

powder

surface area

~1000 m2/g , BET

unit cell size

4.5-4.8 nm

pore size

0.98 cm3/g pore volume, 2.1-2.7 nm pore size

bp

2230 °C (lit.)

mp

>1600 °C (lit.)

bulk density

0.34 g/mL

application(s)

battery manufacturing

SMILES string

O=[Si]=O

InChI

1S/O2Si/c1-3-2

InChI key

VYPSYNLAJGMNEJ-UHFFFAOYSA-N

General description

Silica, mesostructured (MCM-41) is a part of low-density organized mesoporous silicate system which has a 2D hexagonal phase, prepared in the presence of quaternary ammonium halide surfactant. It has ordered and large pores with diameter in the range 1.5-10 nm and specific surface area of 1500 m2/g.

Application

MCM-41 may be used as a base material that can be assembled with platinum complexes to develop luminescent oxygen sensing materials. It may also be used as an adsorbent in CO2 capture application. Surface functionalized MCM-41 may be used as a catalyst in the synthesis of bisphenol A.


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Storage Class

13 - Non Combustible Solids

wgk

nwg

flash_point_f

Not applicable

flash_point_c

Not applicable


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Substances Subject to be Indicated Names

ishl_indicated

Substances Subject to be Notified Names

ishl_notified

643645-25G:4.548173945194E12 + 643645-5G:4.5481739452E12

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Articles

Mesoporous silica used in wastewater remediation, air cleaning, catalysis, bio-catalysis, and drug delivery.

廃液処理、空気浄化、触媒、生体触媒、薬物送達で使用されるメソポーラスシリカ。

シリコンは、既知の材料の中で最も高い容量を有し、比較的低い作動電位を示すなどの利点があることから、リチウムイオン電池用の最も有望な負極材料の1つです。

View All Articles

Chiral mesostructured silica nanofibers of MCM-41
Wang B, et al.
Angewandte Chemie (International ed. in English), 45(13), 2088-2090 (2006)
Effect of surface functionalization of MCM-41-type mesoporous silica nanoparticles on the endocytosis by human cancer cells
Slowing I, et al.
Journal of the American Chemical Society, 128(46), 14792-14793 (2006)
Oxygen sensing materials based on mesoporous silica MCM-41 and Pt (II)-porphyrin complexes
Zhang H, et al.
Journal of Materials Chemistry, 15(31), 3181-3186 (2005)