703486
sec-Butylmagnesium chloride lithium chloride complex solution
1.2 M in THF
Synonym(s):
2-Butylmagnesium chloride lithium chloride complex, Turbo Grignard
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About This Item
form
liquid
reaction suitability
reaction type: Grignard Reaction
concentration
1.2 M in THF, 14 % (w/w)
density
0.973 g/mL at 25 °C
SMILES string
[Li]Cl.CCC(C)[Mg]Cl
InChI
1S/C4H9.2ClH.Li.Mg/c1-3-4-2;;;;/h3H,4H2,1-2H3;2*1H;;/q;;;2*+1/p-2
InChI key
ZMDHAYOBNXOYEU-UHFFFAOYSA-L
Application
Legal Information
signalword
Danger
target_organs
Central nervous system, Respiratory system
supp_hazards
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 1
flash_point_f
-6.7 °F
flash_point_c
-21.5 °C
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 1
Regulatory Listings
Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.
Class I Designated Chemical Substances
prtr
Group 3: Spontaneously combustible substances and water- reactive materials + Materials containing Organometallic compounds + Hazardous rank I + 1st spontaneously combustible materials and water reactive materials
fsl
Substances Subject to be Indicated Names
ishl_indicated
Substances Subject to be Notified Names
ishl_notified
703486-100ML:4548173298016 + 703486-800ML:4548173298023 + 703486-VAR: + 703486-BULK:
jan
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Articles
Salt additives increase both the rate and the efficiency of the Mg-halogen exchange reaction. The most effective reagents are generated with R-MgCl (R = i-Pr, s-Butyl) and 1.0 equiv of LiCl.