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Merck

710733

2,2,5-Trimethyl-4-phenyl-3-azahexane-3-nitroxide

Synonym(s):

1,1-Dimethylethyl-2-methyl-1-phenylpropyl nitroxide, tert-Butyl 1-phenyl-2-methylpropyl nitroxide, NMP universal alkoxyamine nitroxide

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About This Item

Empirical Formula (Hill Notation):
C14H22NO
CAS Number:
Molecular Weight:
220.33
UNSPSC Code:
12162002
PubChem Substance ID:
MDL number:
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refractive index

n20/D 1.515

density

0.953 g/mL at 25 °C

storage temp.

−20°C

SMILES string

CC(C)C(N([O])C(C)(C)C)c1ccccc1

InChI

1S/C14H22NO/c1-11(2)13(15(16)14(3,4)5)12-9-7-6-8-10-12/h6-11,13H,1-5H3

InChI key

VGHCMXLEZFMZOZ-UHFFFAOYSA-N

General description

For a synthetic protocol using NMP initiators, contributed by Prof. Karen Wooley, please visit our technology spotlight.

Application

Stable nitroxide radical useful in controlling living radical polymerizations


pictograms

Flame over circleSkull and crossbones

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 3 Oral - Ox. Liq. 3

Storage Class

5.1B - Oxidizing hazardous materials

wgk

WGK 3

flash_point_f

205.0 °F - closed cup

flash_point_c

96.1 °C - closed cup


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Group 4: Flammable liquids + Type 3 petroleums + Hazardous rank III + Water insoluble liquid

fsl

710733-VAR: + 710733-250MG: + 710733-1G: + 710733-BULK:

jan



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Protocols

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

View All Protocols

Articles

ニトロキシドを介したラジカル重合(NMP)の概略とNMP開始剤について、実際のプロトコルを中心にご紹介します。

Micro Review:RAFT(可逆的付加/開裂連鎖移動)重合

Block copolymer synthesis using a commercially available nitroxide-mediated radical polymerization (NMP) initiator

View All Articles