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Merck

722987

2-Cyano-2-propyl benzodithioate

>97% (HPLC)

Synonym(s):

2-Cyanopropan-2-yl benzodithioate

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About This Item

Empirical Formula (Hill Notation):
C11H11NS2
CAS Number:
201611-85-0
Molecular Weight:
221.34
NACRES:
NA.23
PubChem Substance ID:
329763965
UNSPSC Code:
12352100
MDL number:
MFCD09037881

Key Documents

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InChI

1S/C11H11NS2/c1-11(2,8-12)14-10(13)9-6-4-3-5-7-9/h3-7H,1-2H3

SMILES string

CC(C)(SC(=S)c1ccccc1)C#N

InChI key

IDSLBLWCPSAZBL-UHFFFAOYSA-N

assay

>97% (HPLC)

form

solid or liquid

refractive index

n20/D 1.621

mp

28-31 °C

density

1.146 g/mL at 25 °C

storage temp.

2-8°C

Quality Level

100

Related Categories

General description

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

Application

Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerization
RAFT agent for controlled radical polymerization; especially suited for the polymerization of methacrylate and methacrylamide monomers. Chain Transfer Agent (CTA)

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H317

Hazard Classifications

Skin Sens. 1

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

>230.0 °F - closed cup

flash_point_c

> 110 °C - closed cup

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Deleterious substance

pdsc

722987-5G:4548173299563 + 722987-VAR: + 722987-BULK: + 722987-1G:4548173299556

jan

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Certificates of Analysis (COA)

Lot/Batch Number
MKCP5045
MKCN2568
MKCM5874
MKCL7228
MKCM0323

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Laura Marcela Forero Ramirez et al.
Carbohydrate polymers, 224, 115153-115153 (2019-09-02)
A multi-reactive polysaccharide-based transurf (acting both as macro-Chain Transfer Agent and stabilizer) was used to confine RAFT polymerization of methyl methacrylate (MMA) at the oil/water (o/w) miniemulsion interface. Dithiobenzoate groups and hydrophobic aliphatic side chains were introduced onto dextran, conferring
Katharina Nieswandt et al.
Materials (Basel, Switzerland), 12(19) (2019-09-29)
In this work, we present a novel synthetic route to diblock copolymers based on styrene and 3-vinylpyridine monomers. Surfactant-free water-based reversible addition-fragmentation chain transfer (RAFT) emulsion polymerization of styrene in the presence of the macroRAFT agent poly(3-vinylpyridine) (P3VP) is used
Xiaohan Zhang et al.
Langmuir : the ACS journal of surfaces and colloids, 34(27), 7998-8006 (2018-06-28)
Amphiphilic poly( N-(2-hydroxypropyl)methacrylamide) copolymers ( pHPMA) bearing cholesterol side groups in phosphate buffer saline self-assemble into nanoparticles (NPs) which can be used as tumor-targeted drug carriers. It was previously shown by us that human serum albumin (HSA) interacts weakly with
Ryuichi Nakatani et al.
ACS applied materials & interfaces, 9(37), 31266-31278 (2017-03-18)
In this study, a series of perpendicular lamellae-forming poly(polyhedral oligomeric silsesquioxane methacrylate-block-2,2,2-trifluoroethyl methacrylate)s (PMAPOSS-b-PTFEMAs) was developed based on the bottom-up concept of creating a simple yet effective material by tailoring the chemical properties and molecular composition of the material. The
Laure Gevaux et al.
Polymers, 11(2) (2019-04-10)
Fouling Release Coatings are marine antifouling coatings based on silicone elastomers. Contrary to commonly used biocide-based antifouling coatings, they do not release biocides into the marine environment, however, they suffer from poor antifouling efficacy during idle periods. To improve their
View All Related Papers

Articles

RAFT重合によるタンパク質およびペプチドとポリマーとのコンジュゲート

ペプチドやタンパク質のような生体高分子に合成ポリマーを結合させて修飾することで、特性が強化された極めて高度な新しい種類の生体材料が得られています。

双頭型重合剤による機能性バイオマテリアルの合成

双頭型重合剤（dual initiator、二官能性もしくはヘテロ官能性開始剤とも呼ばれます）は、同時重合を独立的かつ選択的に開始できる二つの機能性部位を有しています。

Micro Review：RAFT重合

Micro Review：RAFT（可逆的付加／開裂連鎖移動）重合

Protocols

Concepts and Tools for RAFT Polymerization

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

RAFT Polymerization Procedures

RAFT polymerization offers precise control, enabling tailored synthesis of complex polymer structures.

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

Typical Procedures for Polymerizing via RAFT

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

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Related Content

Bulletin - 722987

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