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Merck

723029

Cyanomethyl dodecyl trithiocarbonate

98% (HPLC)

Synonym(s):

S-Cyanomethyl-S-dodecyltrithiocarbonate

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About This Item

Empirical Formula (Hill Notation):
C15H27NS3
CAS Number:
Molecular Weight:
317.58
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
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InChI

1S/C15H27NS3/c1-2-3-4-5-6-7-8-9-10-11-13-18-15(17)19-14-12-16/h2-11,13-14H2,1H3

SMILES string

CCCCCCCCCCCCSC(=S)SCC#N

InChI key

URUIKGRSOJEVQG-UHFFFAOYSA-N

assay

98% (HPLC)

form

solid

storage temp.

2-8°C

Quality Level

General description

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

>230.0 °F - closed cup

flash_point_c

> 110 °C - closed cup


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Deleterious substance

pdsc

723029-1G:4548173300665 + 723029-BULK: + 723029-5G:4548173300672 + 723029-VAR:

jan


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RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

Articles

ペプチドやタンパク質のような生体高分子に合成ポリマーを結合させて修飾することで、特性が強化された極めて高度な新しい種類の生体材料が得られています。

双頭型重合剤(dual initiator、二官能性もしくはヘテロ官能性開始剤とも呼ばれます)は、同時重合を独立的かつ選択的に開始できる二つの機能性部位を有しています。

Micro Review:RAFT(可逆的付加/開裂連鎖移動)重合

Protocols

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

RAFT polymerization offers precise control, enabling tailored synthesis of complex polymer structures.

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

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