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Merck

723126

Bis(dodecylsulfanylthiocarbonyl) disulfide

≥95%

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About This Item

Empirical Formula (Hill Notation):
C26H50S6
CAS Number:
Molecular Weight:
555.07
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
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Quality Level

assay

≥95%

form

solid

mp

30-35 °C

storage temp.

−20°C

SMILES string

CCCCCCCCCCCCSC(=S)SSC(=S)SCCCCCCCCCCCC

InChI

1S/C26H50S6/c1-3-5-7-9-11-13-15-17-19-21-23-29-25(27)31-32-26(28)30-24-22-20-18-16-14-12-10-8-6-4-2/h3-24H2,1-2H3

InChI key

UUNRYKCXJSDLRD-UHFFFAOYSA-N

General description

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

Application

Precursor for the synthesis of RAFT agents for controlled radical polymerization.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

723126-BULK: + 723126-5G: + 723126-VAR:

jan


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RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

Articles

Micro Review:RAFT(可逆的付加/開裂連鎖移動)重合

RAFT polymerization offers living characteristics to radical polymerization, contributing versatility to reversible deactivation radical polymerization methods.

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

RAFT polymerization uses commercial agents to control polymer properties without cytotoxic heavy metals like ATRP.

Protocols

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

RAFT polymerization offers precise control, enabling tailored synthesis of complex polymer structures.

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

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