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741698

2-(Dodecylthiocarbonothioylthio)-2-methylpropionic acid 3-azido-1-propanol ester

98% (HPLC)

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About This Item

Empirical Formula (Hill Notation):
C20H37N3O2S3
CAS Number:
927816-03-3
Molecular Weight:
447.72
NACRES:
NA.23
PubChem Substance ID:
329765524
UNSPSC Code:
12352100
MDL number:
MFCD22200504
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Quality Level

100

assay

98% (HPLC)

form

liquid

refractive index

n20/D 1.528

density

1.058 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CCCCCCCCCCCCSC(=S)SC(C)(C)C(=O)OCCCN=[N+]=[N-]

InChI

1S/C20H37N3O2S3/c1-4-5-6-7-8-9-10-11-12-13-17-27-19(26)28-20(2,3)18(24)25-16-14-15-22-23-21/h4-17H2,1-3H3

InChI key

HQKDQLOBIDMFQX-UHFFFAOYSA-N

General description

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

Application

Functionalized RAFT agent for controlled radical polymerization; especially suited for the polymerization of styrene, acrylate and acrylamide monomers. Azide group can be used to conjugate to a variety of alkyne-functionalized biomolecules. Chain Transfer Agent (CTA).

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Protocols

Concepts and Tools for RAFT Polymerization

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

Typical Procedures for Polymerizing via RAFT

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

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Articles

RAFT重合によるタンパク質およびペプチドとポリマーとのコンジュゲート

ペプチドやタンパク質のような生体高分子に合成ポリマーを結合させて修飾することで、特性が強化された極めて高度な新しい種類の生体材料が得られています。

Micro Review：RAFT重合

Micro Review：RAFT（可逆的付加／開裂連鎖移動）重合

Protein- and Peptide- Polymer Conjugates by RAFT Polymerization

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

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RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being