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Merck

75990

Palladium on activated charcoal

greener alternative

10% Pd, powder

Synonym(s):

Pd/C

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About This Item

Linear Formula:
Pd
UNSPSC Code:
12141733
eCl@ss:
38191001
PubChem Substance ID:
57652600
NACRES:
NA.22
MDL number:
MFCD03457879

Key Documents

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Product Name

Palladium on activated charcoal, 10% Pd basis

Quality Level

200

form

powder

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

greener alternative product characteristics

Designing Safer Chemicals
Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

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concentration

10% Pd

greener alternative category

Aligned,

SMILES string

[Pd]

InChI

1S/Pd

InChI key

KDLHZDBZIXYQEI-UHFFFAOYSA-N

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Palladium on activated charcoal has been used for the reduction of trimesic acid to form a mixture of cis,cis and cis,trans isomers of 1,3,5-cyclohexanetricarboxylic acid. It can also be used for the conversion of benzylic and allylic alcohols into the corresponding carbonyl compounds in the presence of olefins as hydrogen acceptors.

Other Notes

Catalyst for dehydrogenations

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H315,H319

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Group 2: Flammable solids + Metal powder + Hazardous rank II + 1st combustible solid

fsl

75990-VAR: + 75990-1G: + 75990-50G: + 75990-10G: + 75990-BULK:

jan

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Certificates of Analysis (COA)

Lot/Batch Number
1408980
1371679
1346740
1318547
1309330

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Brown, H. C.; Rangaishenvi, M. V.
Tetrahedron Letters, 31, 7115-7115 (1990)
Variable gelation time and stiffness of low-molecular-weight hydrogels through catalytic control over self-assembly.
Poolman JM, et al.
Nature Protocols, 9(4), 977-977 (2014)
Effenberger, F.; Muller, W.et al.
The Journal of Organic Chemistry, 55, 3064-3064 (1990)
Orlek, B. S.; Wadsworth, H. et al.
Tetrahedron Letters, 32, 1241-1241 (1991)
Iida, H.; Watanabe, Y.; Kibayashi, C.
Journal of the American Chemical Society, 107, 5534-5534 (1985)
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