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Merck

763543

1,1,1-Tris[(dodecylthiocarbonothioylthio)-2-methylpropionate]ethane

98% (HPLC)

Synonym(s):

3 arm star polymer RAFT agent, Tris(DDMAT)

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About This Item

Empirical Formula (Hill Notation):
C56H102O6S9
Molecular Weight:
1159.99
NACRES:
NA.23
PubChem Substance ID:
329767061
UNSPSC Code:
12352100
MDL number:
MFCD22572686

Key Documents

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InChI

1S/C56H102O6S9/c1-11-14-17-20-23-26-29-32-35-38-41-66-50(63)69-53(4,5)47(57)60-44-56(10,45-61-48(58)54(6,7)70-51(64)67-42-39-36-33-30-27-24-21-18-15-12-2)46-62-49(59)55(8,9)71-52(65)68-43-40-37-34-31-28-25-22-19-16-13-3/h11-46H2,1-10H3

SMILES string

CCCCCCCCCCCCSC(=S)SC(C)(C)C(=O)OCC(C)(COC(=O)C(C)(C)SC(=S)SCCCCCCCCCCCC)COC(=O)C(C)(C)SC(=S)SCCCCCCCCCCCC

InChI key

HYZIWJXWRIAPNA-UHFFFAOYSA-N

assay

98% (HPLC)

form

liquid

refractive index

n20/D 1.5314

density

1.085 g/mL at 25 °C

storage temp.

2-8°C

Quality Level

100

Related Categories

Application

Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerization

General description

Functionalized RAFT agent for controlled radical polymerization; especially suited for the polymerization of styrene; acrylate and acrylamide monomers. For use in advanced material (rheology; etc) and biomaterial (nanomedicine) applications. Chain Transfer Agent (CTA)
Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

No data available

flash_point_c

No data available

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

763543-BULK: + 763543-VAR: + 763543-1G:

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Certificates of Analysis (COA)

Lot/Batch Number
MKBL1528

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Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

Articles

RAFT重合によるタンパク質およびペプチドとポリマーとのコンジュゲート

ペプチドやタンパク質のような生体高分子に合成ポリマーを結合させて修飾することで、特性が強化された極めて高度な新しい種類の生体材料が得られています。

Protein- and Peptide- Polymer Conjugates by RAFT Polymerization

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

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