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Merck

772410

PTB7

greener alternative

average Mw 80,000-200,000, PDI ≤3.0

Synonym(s):

Poly({4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl}{3-fluoro-2-[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophenediyl})

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About This Item

Empirical Formula (Hill Notation):
(C41H53FO4S4)n
CAS Number:
NACRES:
NA.23
UNSPSC Code:
12352103
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description

Band gap: 1.84 eV

form

solid

mol wt

average Mw 80,000-200,000

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

solubility

chlorobenzene: soluble, chloroform: soluble, dichlorobenzene: soluble

λmax

680 nm (thin film)

orbital energy

HOMO -5.15 eV , LUMO -3.31 eV 

Mw/Mn

2.4 +/- 0.6

PDI

≤3.0

greener alternative category

Quality Level

Application

High-Efficiency Organic Solar Cells (OPVs)
OPV Device Structure: ITO/PEDOT:PSS/PTB7 :PC71BM/Ca/Al
  • JSC = 14.9 mA/cm2
  • VOC = 0.75 V
  • FF = 0.69
  • PCE = 7.4%
It is majorly used as an active layer that enhances the overall performance by increasing the light absorption and improving the electron mobility of polymeric solar cells (PSCs).

General description

PTB7 is a semiconducting polymer used in organic photovoltaics with an energy efficiency of 9.15%. It can act as an electron donor with narrow optical band gaps and excellent π-π conjugation while forming a nanocomposite with fullerenes.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product belongs to Enabling category of greener alternatives thus aligns with "Design for energy efficency". Hole transport organic materials allow perfect energy level alignment with the absorber layer and therefore efficient charge collection, are prone to degradation in ambient conditions.Click here for more information.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

772410-BULK: + 772410-100MG: + 772410-VAR:

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Highly efficient tandem polymer photovoltaic cells
Sista S, et al.
Advanced Materials, 22(3), 380-383 (2010)
For the bright future-bulk heterojunction polymer solar cells with power conversion efficiency of 7.4%.
Yongye Liang et al.
Advanced materials (Deerfield Beach, Fla.), 22(20), E135-E138 (2010-07-20)
Sylvia J Lou et al.
Journal of the American Chemical Society, 133(51), 20661-20663 (2011-12-01)
Processing additives are used in organic photovoltaic systems to optimize the active layer film morphology. However, the actual mechanism is not well understood. Using X-ray scattering techniques, we analyze the effects of an additive diiodooctane (DIO) on the aggregation of

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