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Merck

902896

Black phosphorus

>=20 micro gram/ml in NMP

Synonym(s):

2D Black phosphorus, Phosphorene

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About This Item

Linear Formula:
P
NACRES:
NA.23
UNSPSC Code:
12161600

Key Documents

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liquid

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Application

BP is a two dimensional (2D) p-type material, which shows high hole mobility up to 1000 cm2V-1s-1. It can be used in the fabrication of energy storage devices such as lithium-ion batteries. BP can also be used in a variety of biomedical applications such as photodynamic therapy.
Owing to the unique properties such as thickness dependent tunable band gap, strong in-plane anisotropy, and high carrier mobility, 2D-black phosphorous has attracted significant attention recently. The applications of 2D-black phosphorous extend from electronics, to optoelectronics, spintronics, thermoelectrics and storage devices.

Disclaimer

Material is very oxygen sensitive. Please handle under inert atmosphere.

General description

Black phosphorus, also known as phosphorene, is a stable allotrope of phosphorus with semiconducting properties. It has a good mechanical property and a tunable band structure. BP also has good anisotropic thermal, electrical and optical properties.

pictograms

Health hazardExclamation mark
GHS08,GHS07

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 1

flash_point_f

195.8 °F - closed cup

flash_point_c

91 °C - closed cup

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Class I Designated Chemical Substances

prtr

Group 4: Flammable liquids + Type 3 petroleums + Hazardous rank III + Water insoluble liquid

fsl

Substances Subject to be Indicated Names

ishl_indicated

Substances Subject to be Notified Names

ishl_notified

902896-20ML:4548173367705 + 902896-BULK: + 902896-VAR:

jan

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Certificates of Analysis (COA)

Lot/Batch Number
MKCQ5764
MKCN4910
MKCH4381

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Production of few-layer phosphorene by liquid exfoliation of black phosphorus.
Brent, et al.
Chemical Communications (Cambridge, England), 50, 13338-13341 (2014)
Applications of Phosphorene and Black Phosphorus in Energy Conversion and Storage Devices.
Pang J, et al.
Advanced Energy Materials, 8, 1702093-1702093 (2018)
Phosphorene: An Unexplored 2D Semiconductor with a High Hole Mobility.
Liu H, et al.
ACS Nano, 8, 4033-4041 (2014)
Phosphorene: Synthesis, Scale-Up, and Quantitative Optical Spectroscopy.
Woomer, et al.
ACS Nano, 9, 8869-8884 (2015)
Recent advances in synthesis, properties, and applications of phosphorene.
Akhtar M, et al.
NPJ 2D materials and applications, 5, 1-1 (2017)
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