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Merck

B1252

Boron trifluoride-methanol solution

14% in methanol

Synonym(s):

BF3 methanol, BF3MeOH, Boron Trifluoride - Methanol Complex, Boron fluoride methanol, Boron trifluoride methanol, Boron trifluoride-methanol complex, Borontrifluoride methanol, Trifluoroborane

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About This Item

Linear Formula:
BF3 · MeOH
CAS Number:
Molecular Weight:
99.85
UNSPSC Code:
12352104
NACRES:
NA.23
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3611499
Concentration:
12-16% (titration by NaOH), 14% in methanol
Form:
liquid
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form

liquid

Quality Level

reaction suitability

reagent type: catalyst
core: boron

concentration

12-16% (titration by NaOH), 14% in methanol

density

0.859 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CO.FB(F)F

InChI

1S/CH4O.BF3/c1-2;2-1(3)4/h2H,1H3;

InChI key

JBXYCUKPDAAYAS-UHFFFAOYSA-N

General description

Boron trifluoride-methanol (BF-M) is an esterification reagent. BF-M is a powerful acidic catalyst for the esterification of the fatty acids. It easily cleaves acetylated dyes resulting in free amino groups. BF-M catalyzed trans esterification of vegetable oils forms biodiesel.

Application

Used in the deactylation of acetanilides.It is also used to study the synthesis of amino group containing cyanine dyes of different types and to prepare fatty acid methyl esters.

Packaging

Bottle with screw-cap closure.


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Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT RE 2 Inhalation - STOT SE 1

target_organs

Eyes,Central nervous system, Kidney

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

49.5 °F

flash_point_c

9.7 °C

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Class I Designated Chemical Substances

prtr

Group 4: Flammable liquids + Type 1 petroleums + Hazardous rank II + Water insoluble liquid

fsl

Substances Subject to be Indicated Names

ishl_indicated

Substances Subject to be Notified Names

ishl_notified

B1252-1L:4.548173188706E12 + B1252-5ML:4.548173188737E12 + B1252-100ML:4.54817318869E12 + B1252-500ML:4.54817318872E12 + B1252-250ML:4.548173188713E12

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