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Merck

P20009

Phenylboronic acid

95%

Synonym(s):

Benzeneboronic acid, Dihydroxyphenylborane, NSC 66487, Phenyl-boric acid, Phenylboric acid, Phenyldihydroxyborane

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About This Item

Linear Formula:
C6H5B(OH)2
CAS Number:
Molecular Weight:
121.93
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
EC Number:
202-701-9
Beilstein/REAXYS Number:
970972
MDL number:
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InChI

1S/C6H7BO2/c8-7(9)6-4-2-1-3-5-6/h1-5,8-9H

InChI key

HXITXNWTGFUOAU-UHFFFAOYSA-N

SMILES string

OB(O)c1ccccc1

assay

95%

form

crystals

mp

216-219 °C (lit.)

Quality Level

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Application

Reagent used for
  • Rhodium-catalyzed intramolecular amination
  • Pd-catalyzed direct arylation
  • Mizoroki-Heck and Suzuki-Miyaura coupling reactions catalyzed by palladium nanoparticles
  • Palladium-catalyzed stereoselective Heck-type reaction
  • Highly effective Palladium-catalyzed arylation Suzuki-Miyaura cross-coupling in water

Reagent used in Preparation of
  • Ni(II) pincer complex and Pd(II) pyridoxal hydrazone metallacycles as catalysts for the Suzuki-Miyaura cross-coupling reactions
  • N-type polymers for all-polymer solar cells
  • Novel series of potent and selective mTOR kinase inhibitors
  • Inhibitors of lactate dehydrogenase against cancer cell proliferation

Other Notes

Contains varying amounts of phenylboronic anhydride

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Class I Designated Chemical Substances

prtr

P20009-BULK: + P20009-50G: + P20009-5G: + P20009-VAR: + P20009-250G: + P20009-10G:

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The Journal of Organic Chemistry, 59, 5524-5524 (1994)
Tetrahedron Letters, 47, 9267-9267 (2006)
Tetrahedron Letters, 47, 9239-9239 (2006)
Tetrahedron Letters, 35, 3277-3277 (1994)
Journal of the American Chemical Society, 116, 7449-7449 (1994)

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