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Merck

T62405

Silver trifluoroacetate

98%

Synonym(s):

Trifluoroacetic acid silver salt

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About This Item

Linear Formula:
CF3COOAg
CAS Number:
Molecular Weight:
220.88
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
EC Number:
221-004-0
Beilstein/REAXYS Number:
3634022
MDL number:
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Quality Segment

assay

98%

form

powder

reaction suitability

core: silver, reagent type: catalyst

mp

257-260 °C (dec.) (lit.)

SMILES string

FC(F)(F)C(=O)O[Ag]

InChI

1S/C2HF3O2.Ag/c3-2(4,5)1(6)7;/h(H,6,7);/q;+1/p-1

InChI key

KZJPVUDYAMEDRM-UHFFFAOYSA-M

General description

Silver trifluoroacetate is the silver salt of trifluoroacetic acid and appears as a light-yellow crystalline powder. Its excellent solubility in water, acetone, and ethanol makes it easy to handle in solution-based processes. It is often used as a silver source for creating thin films on electronic substrates via techniques like spin-coating, dip-coating, or spray-coating, forming conductive silver layers.

Application

Silver trifluoroacetate is used
  • As a precursor to synthesize ultrasmall icosahedral silver nanoparticles with precise size control and high monodispersed, ideal for advanced applications in plasmonic sensing, nanoelectronics, and biomedical diagnostics.
  • As a co-precursor to promote the formation of silver nanocluster nodes, enabling the controlled self-assembly of coordination polymers designed for advanced applications in optoelectronics and molecular sensing.
  • As a silver source to coat gold ultrathin nanorods with a single atomic silver layer, fine-tuning their optical properties for use in plasmonic sensing and nanophotonic.
  • As a bifunctional reagent and it serves as both a convenient in situ CO source and an oxidant in the reaction.

Features and Benefits

High silver loading (48.7%) increases the availability of active sites for catalysis, leading to more efficient conversion of reactants into products as more Silver atoms are involved in the reaction.


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Danger

hcodes

Hazard Classifications

Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Substances Subject to be Indicated Names

ishl_indicated

Substances Subject to be Notified Names

ishl_notified

T62405-5G:4.548173951973E12 + T62405-25G:4.548173951966E12

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