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Merck

1.04944

Potassium chlorate

for analysis EMSURE® ACS,Reag. Ph Eur

Synonym(s):

Potassium chlorate

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About This Item

Empirical Formula (Hill Notation):
ClKO3
CAS Number:
Molecular Weight:
122.55
UNSPSC Code:
12352302
EC Index Number:
223-289-7
NACRES:
NA.21
MDL number:
Assay:
≥99.0% (silver nitrate titration)
Grade:
ACS reagent
Form:
solid
Solubility:
water: soluble (completely 69.9 g/l at 20 °C (68 °F))
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grade

ACS reagent

Quality Segment

agency

reag. Ph. Eur.

product line

EMSURE®

assay

≥99.0% (silver nitrate titration)

form

solid

potency

1870 mg/kg LD50, oral (Rat)

impurities

≤0.005% Insoluble matter

pH

5.6 (20 °C, 73 g/L in H2O)

bp

400 °C (decomposition)

mp

356 °C

solubility

water: soluble (completely 69.9 g/l at 20 °C (68 °F))

density

2.32 g/cm3 at 20 °C

bulk density

1200‑1400 kg/m3

anion traces

bromate (BrO3-): ≤0.015%, chloride (Cl-): ≤0.001%, sulfate (SO42-): ≤0.002%

cation traces

As: ≤0.00005%, Ca: ≤0.002%, Fe: ≤0.0003%, Mg: ≤0.001%, Na: ≤0.01%, heavy metals (as Pb): ≤0.0005%

storage temp.

2-30°C

SMILES string

[K+].[Cl](=O)(=O)[O-]

InChI

1S/ClHO3.K/c2-1(3)4;/h(H,2,3,4);/q;+1/p-1

InChI key

VKJKEPKFPUWCAS-UHFFFAOYSA-M

Application


  • Inorganic oxidizer detection from propellants, pyrotechnics, and homemade explosive powders using gradient elution moving boundary electrophoresis.: Details the effective identification of potassium chlorate in various explosive formulations using electrophoresis, contributing to safer handling and forensic applications (Krauss et al., 2021).


Analysis Note

Assay (argentometric): ≥ 99.0 %
Identity: passes test
Insoluble matter: ≤ 0.005 %
Bromate (BrO₃): ≤ 0.015 %
Chloride (Cl): ≤ 0.001 %
Sulfate (SO₄): ≤ 0.002 %
Heavy metals (as Pb): ≤ 0.0005 %
As (Arsenic): ≤ 0.00005 %
Ca (Calcium): ≤ 0.002 %
Fe (Iron): ≤ 0.0003 %
Mg (Magnesium): ≤ 0.001 %
Na (Sodium): ≤ 0.01 %

Legal Information

EMSURE is a registered trademark of Merck KGaA, Darmstadt, Germany


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signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Ox. Sol. 1

Storage Class

5.1A - Strongly oxidizing hazardous materials

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Deleterious substance

pdsc

Oxidizing solids + Chlorates + Hazardous rank I + 1st oxidizing solid

fsl

Substances Subject to be Indicated Names

ishl_indicated

Substances Subject to be Notified Names

ishl_notified



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Global Trade Item Number

SKUGTIN
1.04944.010004022536057774
1.04944.050004022536057781