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Merck

248649

Hydriodic acid

contains ≤1.5% hypophosphorous acid as stabilizer, ACS reagent, ≥47.0%

Synonym(s):

Hydriotic acid

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About This Item

Empirical Formula (Hill Notation):
HI
CAS Number:
Molecular Weight:
127.91
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352106
MDL number:
Concentration:
≥47.0%
Form:
liquid
Grade:
ACS reagent
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grade

ACS reagent

Quality Segment

form

liquid

contains

≤1.5% hypophosphorous acid as stabilizer

concentration

≥47.0%

bp

127 °C (lit.)

density

1.5 g/mL at 25 °C

anion traces

bromide, chloride (as Cl-): ≤0.05%, sulfate (SO42-): ≤0.005%

cation traces

Fe: ≤0.001%, heavy metals: ≤0.001%

storage temp.

2-8°C

SMILES string

I

InChI

1S/HI/h1H

InChI key

XMBWDFGMSWQBCA-UHFFFAOYSA-N

Application

Hydriodic acid is a solution of hydrogen iodide in water. It is a strong acid. It is commonly used as a reagent in various reactions such as:
  • electrophilic hydriodination of alkenes and alkynes
  • cleavage of epoxides, ethers, and acetals; conversion of alcohols to iodides   
  • reducing agent for many groups including quinones, α-diketones, α-ketols, α-halo ketones, α-diazo ketones, and sulfoxides      
  • reductive cyclization of keto acids

Hydriodic acid (hypophosphorus acid as a stabilizer) can be used for the fabrication of benzylammonium hybrid layered metal-halide perovskites for spintronic and nonlinear optical applications


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pictograms

CorrosionEnvironment

signalword

Danger

Hazard Classifications

Aquatic Chronic 2 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Deleterious substance

pdsc

Substances Subject to be Indicated Names

ishl_indicated

Substances Subject to be Notified Names

ishl_notified

248649-5ML:4.548173252292E12 + 248649-500ML:4.548173124421E12 + 248649-100ML:4.548173124414E12

jan



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