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Merck

339261

Hydrofluoric acid

48 wt. % in H2O, ≥99.99% trace metals basis

Synonym(s):

HF

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About This Item

Empirical Formula (Hill Notation):
HF
CAS Number:
7664-39-3
Molecular Weight:
20.01
NACRES:
NA.21
PubChem Substance ID:
329754538
UNSPSC Code:
12352106
MDL number:
MFCD00011346
Assay:
≥99.99% trace metals basis
Concentration:
48 wt. % in H2O
Form:
liquid

Key Documents

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Quality Level

200

vapor density

1.27 (vs air)

vapor pressure

25 mmHg ( 20 °C)

assay

≥99.99% trace metals basis

form

liquid

concentration

48 wt. % in H2O

density

1.15 g/mL at 25 °C (lit.)

SMILES string

[H+].[F-]

InChI

1S/FH/h1H

InChI key

KRHYYFGTRYWZRS-UHFFFAOYSA-N

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General description

Hydrofluoric acid (HF) is the 48% solution of HF in water. It is weakly acidic in nature. Aqueous HF is mostly used in etching silicon in semiconductors and producing inorganic fluoride compounds. HF can also be used as fluorinating and deprotecting agent. As fluorination agent it also forms complexes with organic bases.

Application

Hydrofluoric acid is used:
  • To compose the electrolyte for the synthesis of TiO2 nanotube arrays.
  • As etchant for the glass fibers.
  • As capping reagent for the synthesis of anatase TiO2 nanocrystals/nanosheets.

pictograms

Skull and crossbonesCorrosion
GHS06,GHS05

signalword

Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Eye Dam. 1 - Skin Corr. 1A

Storage Class

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 2

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Poisonous substance

pdsc

Class I Designated Chemical Substances

prtr

Substances Subject to be Indicated Names

ishl_indicated

Substances Subject to be Notified Names

ishl_notified

339261-100ML:4548173137391 + 339261-100ML-PW: + 339261-VAR: + 339261-BULK: + 339261-4X100ML: + 339261-800ML:4548173137407 + 339261-800ML-PW:

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Highly-ordered TiO2 nanotube arrays up to 220μm in length: use in water photoelectrolysis and dye-sensitized solar cells.
Shankar K, et al.
Nanotechnology, 18(6), 065707-065707 (2007)
Eagleson M.
Concise Encyclopedia Chemistry, 508-508 (1994)
Anatase TiO2 nanosheet: an ideal host structure for fast and efficient lithium insertion/extraction.
Chen JS and Lou XW.
Electrochemical Communications, 11(12), 2332-2335 (2009)
Francesca Monticelli et al.
Dental materials : official publication of the Academy of Dental Materials, 22(7), 602-609 (2005-11-18)
To verify the influence of different etching procedures of the post-surface on microtensile bond strength values between fiber posts and composite core materials. 60 DT Light Posts were divided into 10 subgroups using five different chemical surface treatments and two
Barry Greenberg et al.
JACC. Heart failure, 2(1), 84-92 (2014-03-14)
Impaired cardiac isoform of sarco(endo)plasmic reticulum Ca(2+) ATPase (SERCA2a) activity is a key abnormality in heart failure patients with reduced ejection fraction. The CUPID 2 (Calcium Up-Regulation by Percutaneous Administration of Gene Therapy in Cardiac Disease Phase 2b) trial is
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