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Merck

342793

Magnesium oxide

≥99% trace metals basis, -325 mesh

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About This Item

Linear Formula:
MgO
CAS Number:
Molecular Weight:
40.30
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352303
EC Number:
215-171-9
MDL number:
Assay:
≥99% trace metals basis
Form:
powder
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Quality Level

assay

≥99% trace metals basis

form

powder

reaction suitability

reagent type: catalyst
core: magnesium

loss

10% loss on ignition, 1000°C (absorbed H2O and CO2)

particle size

-325 mesh

mp

2852 °C (lit.)

SMILES string

O=[Mg]

InChI

1S/Mg.O

InChI key

CPLXHLVBOLITMK-UHFFFAOYSA-N

General description

Magnesium oxide is a mild basic reagent used in acylations, alkylations, oxidations, reductions, formation of heterocycles, ring-opening of tertiary amines, nitration of aromatic acetals, hydrohalogenation, dehydrohalogenation, carbonylation of organomercurials, and serves as a leaving group to form alkenes.

Application

Magnesium oxide can be used as a catalyst in the:
  • Dehydrogenation of n-octane to synthesize octenes.
  • Solvent-free Knoevenagel condensation of aromatic aldehydes and ethyl cyanoacetate to synthesize electrophilic olefins.

Analysis Note

Purity based on metallic impurity content.


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Storage Class

11 - Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Substances Subject to be Indicated Names

ishl_indicated

Substances Subject to be Notified Names

ishl_notified



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Certificates of Analysis (COA)

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Effect of different catalyst supports on the (n, m) selective growth of single-walled carbon nanotube from Co-Mo catalyst.
Wang B, et al.
J. Mater. Sci., 44(12), 3285-3295 (2009)
Eagleson M.
Concise Encyclopedia Chemistry, 495-495 (1994)
Synthesis of ethylene and ethane by partial oxidation of methane over lithium-doped magnesium oxide.
Ito T and Lunsford JH.
Nature, 721-722 (1985)