190780
トリクロロ酢酸ナトリウム
97%
別名:
NaTCA, TCA ナトリウム塩, トリクロロ酢酸 ナトリウム塩
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この商品について
化学式:
CCl3CO2Na
CAS番号:
分子量:
185.37
UNSPSC Code:
12352302
NACRES:
NA.22
PubChem Substance ID:
EC Number:
211-479-2
Beilstein/REAXYS Number:
3773249
MDL number:
Assay:
97%
Application
トリクロロ酢酸ナトリウムとトリクロロ酢酸（TCA）は、ジメチルホルムアミド（DMF）中でアルデヒドの存在下で迅速な脱炭酸反応を起こして求核性のあるトリクロロメチルアニオンを形成し、このアニオンはその後アルデヒドに結合してトリクロロメチルカルビノールを形成します。また、非プロトン溶媒中ではオレフィン存在下で熱脱炭酸を起こして中間体であるジクロロカルベンが生成します。
signalword
Warning
hcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - STOT SE 3
target_organs
Respiratory system
保管分類
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
The thermal decarboxylation of alkali trichloroacetates in aprotic solvents. II. Decarboxylation in the presence of olefins.
Wagner WM
Rec. Trav. Chim., 80(7), 740-746 (1961)
Paul L A M Corstjens et al.
Parasitology, 141(14), 1841-1855 (2014-06-17)
The potential of various quantitative lateral flow (LF) based assays utilizing up-converting phosphor (UCP) reporters for the diagnosis of schistosomiasis is reviewed including recent developments. Active infections are demonstrated by screening for the presence of regurgitated worm antigens (genus specific
Pierre E Galand et al.
Molecular ecology, 24(23), 5785-5795 (2015-08-21)
Understanding the link between community diversity and ecosystem function is a fundamental aspect of ecology. Systematic losses in biodiversity are widely acknowledged but the impact this may exert on ecosystem functioning remains ambiguous. There is growing evidence of a positive
Two effective procedures for the synthesis of trichloromethyl ketones, useful precursors of chiral ?-amino and ?-hydroxy acids.
Corey EJ
Tetrahedron Letters, 33(24), 3435-3438 (1992)
Arun A Azad et al.
Clinical cancer research : an official journal of the American Association for Cancer Research, 21(10), 2315-2324 (2015-02-26)
Although novel agents targeting the androgen-androgen receptor (AR) axis have altered the treatment paradigm of metastatic castration-resistant prostate cancer (mCRPC), development of therapeutic resistance is inevitable. In this study, we examined whether AR gene aberrations detectable in circulating cell-free DNA
ライフサイエンス、有機合成、材料科学、クロマトグラフィー、分析など、あらゆる分野の研究に経験のあるメンバーがおります。.
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