240907
亜リン酸トリメチル
≥99%, liquid
別名:
P(OMe)3, トリメトキシホスフィン, 亜リン酸メチル
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この商品について
化学式:
(CH3O)3P
CAS番号:
分子量:
124.08
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352108
EC Number:
204-471-5
MDL number:
Beilstein/REAXYS Number:
956570
製品名
亜リン酸トリメチル, ≥99%
InChI key
CYTQBVOFDCPGCX-UHFFFAOYSA-N
InChI
1S/C3H9O3P/c1-4-7(5-2)6-3/h1-3H3
SMILES string
COP(OC)OC
vapor density
4.3 (vs air)
vapor pressure
17 mmHg ( 20 °C)
assay
≥99%
form
liquid
reaction suitability
reagent type: ligand
reaction type: Heck Reaction
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling
refractive index
n20/D 1.408 (lit.)
bp
111-112 °C (lit.)
mp
−78 °C (lit.)
density
1.052 g/mL at 25 °C (lit.)
Quality Level
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関連するカテゴリー
Application
亜リン酸トリメチルは、アリルイリジウム1,5-シクロオクタジエン錯体との直接反応によるアリルリジウム亜リン酸錯体の合成における配位子として使用できます。
General description
亜リン酸トリメチルは、重合触媒、コーティング添加剤、および難燃剤合成の中間体として一般的に使用される有機リン化合物です。また、アミド形成における活性化試薬としても使用されます。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
supp_hazards
保管分類
3 - Flammable liquids
wgk
WGK 1
flash_point_f
82.4 °F - closed cup
flash_point_c
28 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
D H Barton et al.
Bioorganic & medicinal chemistry, 2(4), 259-266 (1994-04-01)
In harmony with our studies on the activation of hydrocarbons by Gif chemistry, we have, in the first part of this paper, studied the mechanism of the lipoxygenase enzymes using soybean lipoxygenase as a model. We have shown with trimethyl
Bangwei Ding et al.
Journal of the American Chemical Society, 125(11), 3248-3259 (2003-03-13)
Trimethyl phosphite, (MeO)(3)P, is introduced as an efficient and selective trap in oxiranylcarbinyl radical (2) systems, formed from haloepoxides 8-13 under thermal AIBN/n-Bu(3)SnH conditions at about 80 degrees C. Initially, the transformations of 8-13, in the absence of phosphite, to
M A Mehlman et al.
Toxicology and applied pharmacology, 72(1), 119-123 (1984-01-01)
Trimethyl phosphite (TMP) is an organophosphorus alkylating agent used primarily in the synthesis of organophosphate compounds. To evaluate teratogenic potential, TMP was administered by gavage to pregnant rats at rates of 16, 49, or 164 mg/kg/day, on gestation Days 6
Tian-lin Zhang et al.
Guang pu xue yu guang pu fen xi = Guang pu, 24(11), 1334-1337 (2005-03-15)
The reactions of unsaturated chloride polyether polyol with trimethyl phosphite have been studied by FTIR, which was prepared by copolymerization of ethanediol, allyl glycidyl ether and epoxychloropropane. The experimental results showed that the reaction included ester-exchange reaction, ester-exchange polymerization and
D Vaughan Griffiths et al.
Organic & biomolecular chemistry, 6(3), 577-585 (2008-01-26)
Dialkyl heteroaroylphosphonates based on thiophene, pyrrole or furan have been prepared and their reactions with trimethyl phosphite investigated. Deoxygenation of the carbonyl groups in these heteroaroylphosphonates occurs to give carbene intermediates, which then undergo further reaction. In the case of
関連コンテンツ
Phosphine Ligand Application Guide
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