264466
2,6-ジフルオロフェノール
98%
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この商品について
化学式:
F2C6H3OH
CAS番号:
分子量:
130.09
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
248-884-9
Beilstein/REAXYS Number:
2043613
MDL number:
Assay:
98%
Form:
solid
InChI key
CKKOVFGIBXCEIJ-UHFFFAOYSA-N
InChI
1S/C6H4F2O/c7-4-2-1-3-5(8)6(4)9/h1-3,9H
SMILES string
Oc1c(F)cccc1F
assay
98%
form
solid
storage condition
protect from light
bp
59-61 °C/17 mmHg (lit.)
mp
38-41 °C (lit.)
solubility
ethanol: soluble 50 mg/mL, clear, colorless to light yellow
functional group
fluoro
storage temp.
2-8°C
Quality Level
Application
2,6-difluorophenol undergoes oxidative polymerization in the presence of the Fe-N,N′-bis(salicylidene)ethylenediamine (salen) complex (catalyst) and hydrogen peroxide (oxidizing agent) to give poly(2,6-difluoro-1,4-phenylene oxide).
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
保管分類
4.1B - Flammable solid hazardous materials
wgk
WGK 3
flash_point_f
136.4 °F - closed cup
flash_point_c
58 °C - closed cup
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
適用法令
試験研究用途を考慮した関連法令を主に挙げております。化学物質以外については、一部の情報のみ提供しています。 製品を安全かつ合法的に使用することは、使用者の義務です。最新情報により修正される場合があります。WEBの反映には時間を要することがあるため、適宜SDSをご参照ください。
第4類:引火性液体 + 第二石油類 + 危険等級III + 非水溶性液体
fsl
264466-VAR: + 264466-5G: + 264466-BULK:
jan
J Qiu et al.
Journal of medicinal chemistry, 42(2), 329-332 (1999-02-02)
3-(Aminomethyl)-2,6-difluorophenol (6) and 4-(aminomethyl)-2, 6-difluorophenol (7) were synthesized in eight and four steps, respectively, starting from 2,6-difluorophenol, to test the potential of the 2,6-difluorophenol moiety to act as a lipophilic bioisostere of a carboxylic acid. Compounds 6 and 7 are
Oxidative Polymerization of 2,6-Difluorophenol to Crystalline Poly(2,6-difluoro-1,4-phenylene oxide).
Ikeda R, et al.
Macromolecules, 33(18), 6648-6652 (2000)
Jiasong Li et al.
Biochemistry, 58(17), 2218-2227 (2019-04-05)
Cysteine dioxygenase (CDO) is a nonheme iron enzyme that adds two oxygen atoms from dioxygen to the sulfur atom of l-cysteine. Adjacent to the iron site of mammalian CDO, there is a post-translationally generated Cys-Tyr cofactor, whose presence substantially enhances
Akira Ohashi et al.
Talanta, 146, 789-794 (2015-12-24)
The solubilities of several cobalt(III) chelates (CoL3) with in supercritical carbon dioxide (SC-CO2) were investigated in the presence of fluorine- and trifluoromethyl-substituted phenols (PhOH) using UV-vis spectrophotometry. Solubility enhancement of CoL3 complexes in SC-CO2 was accomplished by adding PhOH. The
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