348678
パラジウム
foil, thickness 1.0 mm, 99.9% trace metals basis
別名:
Palladium (powder), Palladium black, Palladium element
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この商品について
化学式:
Pd
CAS番号:
分子量:
106.42
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12141733
EC Number:
231-115-6
MDL number:
Quality Level
assay
99.9% trace metals basis
form
foil
composition
Pd
reaction suitability
core: palladium
resistivity
9.96 μΩ-cm, 20°C
thickness
1.0 mm
bp
2970 °C (lit.)
mp
1554 °C (lit.)
density
12.02 g/cm3 (lit.)
SMILES string
[Pd]
InChI
1S/Pd
InChI key
KDLHZDBZIXYQEI-UHFFFAOYSA-N
General description
Palladium and its alloys are used for hydrogen purification in fuel cells. Energy dispersive x-ray diffraction during electrochemical loading of palladium foils with hydrogen and deuterium was studied. Palladium foil was tested as a catalyst for Suzuki-Miyaura cross coupling reaction.
Preparation Note
7.6 g = 25 × 25 mm; 30.4 g = 50 × 50 mm
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保管分類
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
資料
コンビナトリアル材料科学は、系統的な探索を通じて画期的な材料を特定し、材料発見を支援します。
Combinatorial Materials Science identifies breakthrough materials through systematic exploration, aiding material discovery.
Studies on the catalytic ability of palladium wire, foil and sponge in the Suzuki-Miyaura cross coupling
Amoroso F, et al.
Inorgorganica Chimica Acta, 375, 256-262 (2011)
In situ synchrotron energy-dispersive x-ray diffraction study of thin Pd foils with Pd:D and Pd:H concentrations up to 1:1
Knies DL, et al.
Journal of Applied Physics, 112 (2012)
Xuxing Chen et al.
Organic & biomolecular chemistry, 11(16), 2582-2585 (2013-03-19)
A one-pot two-step synthesis of versatile indenones has been developed. This palladium(II)-catalyzed transformation involves generation and condensation of ortho-functionalized 1,2-benzils from 2-(2-arylethynylphenyl)acetonitriles using Ph2SO as the oxidant. The resulting 3-cyanoindenones can be converted to various valuable molecules.