2,2′-アゾビス(2-メチルプロピオンアミジン) 二塩酸塩

Name: 2,2′-アゾビス(2-メチルプロピオンアミジン) 二塩酸塩
Brand: ALDRICH

powder or granules, 97%

別名:

α,α′-アゾジイソブチルアミジン二塩酸塩, AAPH

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この商品について

化学式:

[=NC(CH₃)₂C(=NH)NH₂]₂·2HCl

CAS番号:

2997-92-4

分子量:

271.19

UNSPSC Code:

12162002

NACRES:

NA.23

PubChem Substance ID:

24867630

EC Number:

221-070-0

Beilstein/REAXYS Number:

3718854

MDL number:

MFCD00142725

主要文書

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製品名

2,2′-アゾビス(2-メチルプロピオンアミジン) 二塩酸塩, powder or granules, 97%

InChI key

LXEKPEMOWBOYRF-QDBORUFSSA-N

InChI

1S/C8H18N6.2ClH/c1-7(2,5(9)10)13-14-8(3,4)6(11)12;;/h1-4H3,(H3,9,10)(H3,11,12);2*1H/b14-13+;;

SMILES string

Cl.Cl.CC(C)(\N=N\C(C)(C)C(N)=N)C(N)=N

assay

97%

form

powder or granules

t_1/2

10 hr(56 °C)

mp

175-177 °C (lit.)

solubility

acetone, dioxane, methanol, ethanol, DMSO and water: soluble

Quality Level

200

Application

フリ-ラジカル開始剤
アクリルモノマ-、ビニルモノマ-、およびアリルモノマ-の重合開始剤

Features and Benefits

一次分解してカチオン性ラジカルとなります。UV照射下で分解します。カチオン性界面活性剤と相溶性があります。分解速度はpH 依存性です。

pictograms

GHS02,GHS07,GHS09

signalword

Danger

hcodes

H251,H302,H317,H319,H410

pcodes

P235 - P273 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Self-heat. 1 - Skin Sens. 1

保管分類

4.2 - Pyrophoric and self-heating hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

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Intramolecular hydrogen transfer reactions of thiyl radicals from glutathione: formation of carbon-centered radical at Glu, Cys, and Gly.

Olivier Mozziconacci et al.

Chemical research in toxicology, 25(9), 1842-1861 (2012-06-21)

Glutathione thiyl radicals (GS(•)) were generated in H(2)O and D(2)O by either exposure of GSH to AAPH, photoirradiation of GSH in the presence of acetone, or photoirradiation of GSSG. Detailed interpretation of the fragmentation pathways of deuterated GSH and GSH

A new oxidative stress model, 2,2-azobis(2-amidinopropane) dihydrochloride induces cardiovascular damages in chicken embryo.

Rong-Rong He et al.

PloS one, 8(3), e57732-e57732 (2013-03-08)

It is now well established that the developing embryo is very sensitive to oxidative stress, which is a contributing factor to pregnancy-related disorders. However, little is known about the effects of reactive oxygen species (ROS) on the embryonic cardiovascular system

Characteristics of the spin-trapping reaction of a free radical derived from AAPH: further development of the ORAC-ESR assay.

A Nakajima et al.

Analytical and bioanalytical chemistry, 403(7), 1961-1970 (2012-05-01)

The characteristics of the spin-trapping reaction in the oxygen radical absorbance capacity (ORAC)-electron spin resonance (ESR) assay were examined, focusing on the kind of spin traps. 2,2-Azobis(2-amidinopropane) dihydrochloride (AAPH) was used as a free radical initiator. The spin adducts of

Purification and determination of two novel antioxidant peptides from flounder fish (Paralichthys olivaceus) using digestive proteases.

Ju-Young Ko et al.

Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association, 52, 113-120 (2012-11-14)

We investigated the effects of bioactive-peptides from hydrolysates of flounder fish muscle (FFM) on antioxidant activity. The hydrolysates were prepared by enzymatic reactions of FFM using eight commercial proteases such as papain, pepsin, trypsin, neutrase, alcalase, kojizyme, protamex, and α-chymotrypsin.

Synthesis of 4-methylcoumarin derivatives containing 4,5-dihydropyrazole moiety to scavenge radicals and to protect DNA.

Chuan Xiao et al.

European journal of medicinal chemistry, 53, 159-167 (2012-04-24)

A series of 4-methylcoumarin derivatives containing 4,5-dihydropyrazole moiety were synthesized and their antioxidant activities were evaluated in AAPH (2,2'-azobis(2-amidinopropane hydrochloride))-induced oxidation of DNA, and in trapping DPPH (2,2'-diphenyl-1-picrylhydrazyl) and ABTS(+•) (2,2'-azinobis(3-ethylbenzothiazoline-6-sulfonate) cationic radical), respectively. Among coumarin derivatives, 3a-d and 4a-c

資料

Micro Review：RAFT重合

Micro Review：RAFT（可逆的付加／開裂連鎖移動）重合

Micro Review of RAFT Polymerization

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

プロトコル

Preparation of Monodisperse Polymer Spheres

Polymeric spheres serve as crystal templates. Synthesis methods yield large quantities.

Concepts and Tools for RAFT Polymerization

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

Typical Procedures for Polymerizing via RAFT

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

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ライフサイエンス、有機合成、材料科学、クロマトグラフィー、分析など、あらゆる分野の研究に経験のあるメンバーがおります。.

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2,2′-アゾビス(2-メチルプロピオンアミジン) 二塩酸塩