459798
アリルアルコール
≥98.5%
別名:
2-プロペン-1-オール
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この商品について
化学式:
CH2=CHCH2OH
CAS番号:
分子量:
58.08
UNSPSC Code:
12352200
NACRES:
NA.21
PubChem Substance ID:
EC Number:
203-470-7
Beilstein/REAXYS Number:
605307
MDL number:
製品名
アリルアルコール, ≥98.5%
InChI key
XXROGKLTLUQVRX-UHFFFAOYSA-N
InChI
1S/C3H6O/c1-2-3-4/h2,4H,1,3H2
SMILES string
OCC=C
vapor density
2 (vs air)
vapor pressure
23.8 mmHg ( 25 °C)
assay
≥98.5%
autoignition temp.
712 °F
expl. lim.
18 %
refractive index
n20/D 1.412 (lit.)
bp
96-98 °C (lit.)
mp
−129 °C (lit.)
density
0.854 g/mL at 25 °C (lit.)
functional group
hydroxyl
Quality Level
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Application
肝毒性及び肝幹細胞媒介修復のメカニズムの研究に用いられてきた肝臓障害マウスモデルの誘導に用いられます。
Packaging
signalword
Danger
Hazard Classifications
Acute Tox. 2 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
保管分類
3 - Flammable liquids
wgk
WGK 3
flash_point_f
71.6 °F - closed cup
flash_point_c
22 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hydrosilylation of allyl alcohol with [HSiMe2OSiO1.5]8: octa (3-hydroxypropyldimethylsiloxy) octasilsesquioxane and its octamethacrylate derivative as potential precursors to hybrid nanocomposites.
Zhang C and Laine RM.
Journal of the American Chemical Society, 122(29), 6979-6988 (2000)
Gregory M Mullen et al.
Journal of the American Chemical Society, 136(17), 6489-6498 (2014-04-08)
Partial oxidation of alcohols is a topic of great interest in the field of gold catalysis. In this work, we provide evidence that the partial oxidation of allyl alcohol to its corresponding aldehyde, acrolein, over oxygen-precovered gold surfaces occurs via
Deoxydehydration of glycerol to allyl alcohol catalyzed by rhenium derivatives.
Canale V, et al.
Catalysis Science & Technology, 4(10), 3697-3704 (2014)
James Y Hamilton et al.
Journal of the American Chemical Society, 135(3), 994-997 (2012-12-22)
The first example of Ir-catalyzed asymmetric substitution reaction with vinyl trifluoroborates is described. The direct reaction between branched, racemic allylic alcohols and potassium alkenyltrifluoroborates proceeded with high site selectivity and excellent enantioselectivity (up to 99%) mediated by an Ir-(P,olefin) complex.
Johanna M Larsson et al.
Journal of the American Chemical Society, 135(1), 443-455 (2012-12-04)
The mechanism of the palladium-catalyzed synthesis of allylic silanes and boronates from allylic alcohols was investigated. (1)H, (29)Si, (19)F, and (11)B NMR spectroscopy was used to reveal key intermediates and byproducts of the silylation reaction. The tetrafluoroborate counterion of the
ライフサイエンス、有機合成、材料科学、クロマトグラフィー、分析など、あらゆる分野の研究に経験のあるメンバーがおります。.
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