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この商品について
実験式(ヒル表記法):
C26H34NaO5PS · xH2O
CAS番号:
分子量:
512.57 (anhydrous basis)
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22
MDL number:
製品名
sSPhos,
Quality Level
product line
Buchwald Ligand
form
solid
reaction suitability
reaction type: Cross Couplings, reagent type: ligand
reaction type: Suzuki-Miyaura Coupling
functional group
phosphine
SMILES string
O.[Na+].COc1ccc(c(OC)c1-c2ccccc2P(C3CCCCC3)C4CCCCC4)S([O-])(=O)=O
InChI
1S/C26H35O5PS.Na.H2O/c1-30-22-17-18-24(33(27,28)29)26(31-2)25(22)21-15-9-10-16-23(21)32(19-11-5-3-6-12-19)20-13-7-4-8-14-20;;/h9-10,15-20H,3-8,11-14H2,1-2H3,(H,27,28,29);;1H2/q;+1;/p-1
InChI key
MAPQBSXKBDVINV-UHFFFAOYSA-M
Application
Legal Information
Usage subject to US Patents 6307087 and 6395916.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
保管分類
11 - Combustible Solids
wgk
WGK 3
ppe
dust mask type N95 (US), Eyeshields, Gloves
資料
Buchwald phosphine ligands for C-C, C-N, and C-O bond formation.
関連コンテンツ
Buchwald Portfolio: Palladacycles and Ligands
Phosphine Ligand Application Guide
General catalysts for the Suzuki-Miyaura and Sonogashira coupling reactions of aryl chlorides and for the coupling of challenging substrate combinations in water.
Kevin W Anderson et al.
Angewandte Chemie (International ed. in English), 44(38), 6173-6177 (2005-08-13)
David S Surry et al.
Chemical science, 2(1), 27-50 (2011-01-01)
Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This review attempts to aid the reader in the selection of the best choice of reaction conditions and ligand
Ruben Martin et al.
Accounts of chemical research, 41(11), 1461-1473 (2008-07-16)
The cores of many types of polymers, ligands, natural products, and pharmaceuticals contain biaryl or substituted aromatic structures, and efficient methods of synthesizing these structures are crucial to the work of a broad spectrum of organic chemists. Recently, Pd-catalyzed carbon-carbon
